2022Journal Article ER4 Auteurs : Luyckx, Marie; Blanquet, Mathilde; Isenborghs, Arnaud; Guerriero, Gea; Bidar, Géraldine; Waterlot, Christophe; Douay, Francis; Lutts, Stanley Impact of Silicon and Heavy Metals on Hemp (Cannabis sativa L.) Bast Fibres Properties: An Industrial and Agricultural Perspective In: International Journal of Environmental Research, vol. 16, no. 5, pp. 82, 2022, (ACL). Links @article{luyckx:hal-03851601b,
title = {Impact of Silicon and Heavy Metals on Hemp (Cannabis sativa L.) Bast Fibres Properties: An Industrial and Agricultural Perspective},
author = {Marie Luyckx and Mathilde Blanquet and Arnaud Isenborghs and Gea Guerriero and Géraldine Bidar and Christophe Waterlot and Francis Douay and Stanley Lutts},
url = {https://hal.archives-ouvertes.fr/hal-03851601},
doi = {10.1007/s41742-022-00446-1},
year = {2022},
date = {2022-10-01},
urldate = {2022-10-01},
journal = {International Journal of Environmental Research},
volume = {16},
number = {5},
pages = {82},
publisher = {Springer Verlag},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
|
2022Conference ER4 Auteurs : Schnackenberg, Ashley; Bidar, Géraldine; Bert, Valérie; Cannavo, Patrice; Détriché, Sébastien; Douay, Francis; Guenon, René; Jean-Soro, Liliane; Kohli, Alice; Lebeau, Thierry; Perronnet, Karen; Vidal-Beaudet, Laure; Waterlot, Christophe; Pelfrêne, Aurélie Effects of amendments on the mobility, bioaccessibility, and phytoavailability of As, Cd, Pb, and Zn in contaminated urban kitchen garden soils 11th Conference on Soils of Urban, Industrial, Traffic and Mining Areas (SUITMA), 5-9 September 2022, Berlin (Germany), 2022, (ACTI). Abstract @conference{Schnackenberg2022,
title = {Effects of amendments on the mobility, bioaccessibility, and phytoavailability of As, Cd, Pb, and Zn in contaminated urban kitchen garden soils},
author = {Ashley Schnackenberg and Géraldine Bidar and Valérie Bert and Patrice Cannavo and Sébastien Détriché and Francis Douay and René Guenon and Liliane Jean-Soro and Alice Kohli and Thierry Lebeau and Karen Perronnet and Laure Vidal-Beaudet and Christophe Waterlot and Aurélie Pelfrêne},
year = {2022},
date = {2022-01-01},
booktitle = {11th Conference on Soils of Urban, Industrial, Traffic and Mining Areas (SUITMA), 5-9 September 2022, Berlin (Germany)},
abstract = {Urban gardening is a growing trend that responds to the need for nature in cities, a growing movement towards healthy and sustainable eating and food production, and difficult economic and societal contexts. Both private and community gardens in these areas are often on urban wastelands, along roads, highways, or railways, near industrial sites, and have even sometimes earned the term “guerrilla gardens” for their lack of agronomic regulation. In France, many urban gardens are associated with varying levels of inorganic contaminants hailing from anthropogenic activity or geogenic metal(loid) presence. Moderately metal(loid)- contaminated urban kitchen garden soils can benefit from gentle remediation options including the use of soil amendments, which are able to improve soil function and agronomic quality while decreasing environmental and human health risk. This study first analyses the effects of common doses of a various commercialized soil amendments on the mobility of metalloid(s) in contaminated urban kitchen garden soils. Fourteen different amendments and amendment mixes were tested on three kitchen garden soils with diverse sources of anthropogenic or geogenous contamination and varying physico-chemical characteristics. Amendments from four differing categories were tested, including i) organic amendments like composts, ii) natural fertilizers such as bone meal, crushed horn, and organic poultry manure fertilizer, iii) calcareous amendments including two different limes, and iv) natural siliceous and alumino-silicate amendments, including diatomaceous earth and zeolite. Amendments at varying common doses were evaluated via chemical extractions on their ability to reduce the mobility of metallic elements after multiple weeks of maturation at a constant humidity and temperature. The most pertinent of these amendments were then chosen to be tested in conjunction with a vegetal model grown upon the amended soils in greenhouse conditions. 05.09.– 09.09 2022 Berlin, Germany Changes in physico-chemical soil characteristics, mobility and bioaccessibility of metal(loid)s in the soil, and phytoavailability in the lettuce were then tested. Mobility and bioaccessible metal(loid)s were evaluated with 0.05 M EDTA buffered at a pH of 7, an ammonium nitrate extraction, a 4-phase sequential extraction, and a UBM bioaccessibility test. Phytoavailability was determined using pseudo-total soil and plant metal(loid) contents. The study results show that it is possible to reduce both extractable and phytoavailable metal(oid)s with amendment addition. However, variable effects are seen according to the contaminated soil tested, and differences arise in the presence of a plant model.},
note = {ACTI},
keywords = {ER4},
pubstate = {published},
tppubtype = {conference}
}
Urban gardening is a growing trend that responds to the need for nature in cities, a growing movement towards healthy and sustainable eating and food production, and difficult economic and societal contexts. Both private and community gardens in these areas are often on urban wastelands, along roads, highways, or railways, near industrial sites, and have even sometimes earned the term “guerrilla gardens” for their lack of agronomic regulation. In France, many urban gardens are associated with varying levels of inorganic contaminants hailing from anthropogenic activity or geogenic metal(loid) presence. Moderately metal(loid)- contaminated urban kitchen garden soils can benefit from gentle remediation options including the use of soil amendments, which are able to improve soil function and agronomic quality while decreasing environmental and human health risk. This study first analyses the effects of common doses of a various commercialized soil amendments on the mobility of metalloid(s) in contaminated urban kitchen garden soils. Fourteen different amendments and amendment mixes were tested on three kitchen garden soils with diverse sources of anthropogenic or geogenous contamination and varying physico-chemical characteristics. Amendments from four differing categories were tested, including i) organic amendments like composts, ii) natural fertilizers such as bone meal, crushed horn, and organic poultry manure fertilizer, iii) calcareous amendments including two different limes, and iv) natural siliceous and alumino-silicate amendments, including diatomaceous earth and zeolite. Amendments at varying common doses were evaluated via chemical extractions on their ability to reduce the mobility of metallic elements after multiple weeks of maturation at a constant humidity and temperature. The most pertinent of these amendments were then chosen to be tested in conjunction with a vegetal model grown upon the amended soils in greenhouse conditions. 05.09.– 09.09 2022 Berlin, Germany Changes in physico-chemical soil characteristics, mobility and bioaccessibility of metal(loid)s in the soil, and phytoavailability in the lettuce were then tested. Mobility and bioaccessible metal(loid)s were evaluated with 0.05 M EDTA buffered at a pH of 7, an ammonium nitrate extraction, a 4-phase sequential extraction, and a UBM bioaccessibility test. Phytoavailability was determined using pseudo-total soil and plant metal(loid) contents. The study results show that it is possible to reduce both extractable and phytoavailable metal(oid)s with amendment addition. However, variable effects are seen according to the contaminated soil tested, and differences arise in the presence of a plant model. |
2022Journal Article ER4 Auteurs : Schnackenberg, Ashley; Bidar, Géraldine; Bert, Valérie; Cannavo, Patrice; Détriché, Sébastien; Douay, Francis; Guenon, René; Jean-Soro, Liliane; Kohli, Alice; Lebeau, Thierry; Perronnet, Karen; Vidal-Beaudet, Laure; Waterlot, Christophe; Pelfrêne, Aurélie Effects of Inorganic and Organic Amendments on the Predicted Bioavailability of As, Cd, Pb and Zn in Kitchen Garden Soils In: Advances in Environmental and Engineering Research, vol. 3, pp. 1 - 1, 2022, (ACL). Links @article{schnackenberg:hal-03583334,
title = {Effects of Inorganic and Organic Amendments on the Predicted Bioavailability of As, Cd, Pb and Zn in Kitchen Garden Soils},
author = {Ashley Schnackenberg and Géraldine Bidar and Valérie Bert and Patrice Cannavo and Sébastien Détriché and Francis Douay and René Guenon and Liliane Jean-Soro and Alice Kohli and Thierry Lebeau and Karen Perronnet and Laure Vidal-Beaudet and Christophe Waterlot and Aurélie Pelfrêne},
url = {https://hal.archives-ouvertes.fr/hal-03583334},
doi = {10.21926/aeer.2201004},
year = {2022},
date = {2022-02-01},
urldate = {2022-02-01},
journal = {Advances in Environmental and Engineering Research},
volume = {3},
pages = {1 - 1},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
|
2020Journal Article ER4 Auteurs : Bidar, Géraldine; Pelfrêne, Aurélie; Schwartz, Christophe; Waterlot, Christophe; Sahmer, Karin; Marot, Franck; Douay, Francis Urban kitchen gardens: Effect of the soil contamination and parameters on the trace element accumulation in vegetables – A review In: Science of the Total Environment, vol. 738, pp. 139569, 2020, (ACL). Abstract @article{Bidar2020,
title = {Urban kitchen gardens: Effect of the soil contamination and parameters on the trace element accumulation in vegetables – A review},
author = {Géraldine Bidar and Aurélie Pelfrêne and Christophe Schwartz and Christophe Waterlot and Karin Sahmer and Franck Marot and Francis Douay},
year = {2020},
date = {2020-01-01},
journal = {Science of the Total Environment},
volume = {738},
pages = {139569},
abstract = {Trace element contaminants in kitchen garden soils can contribute
to human exposure through the consumption of homegrown vegetables.
In urban areas, these soils can be contaminated to various degrees
by trace element (TE). They are characterized by a great variability
in their physicochemical parameters due to the high anthropization
level, the wide variety and combination of disturbance sources, aswell
as the diversity of cultivation practices and the large range of
contamination levels. Pollutants can be taken up by vegetables cultivated
in these soils and be concentrated in their edible parts. In this
review, the behavior of vegetables cultivated in contaminated kitchen
gardens is assessed through six examples of the most widely cultivated
vegetables (lettuce, tomato, bean, carrot, radish, potato). The role
of soil parameters that could influence the uptake of As, Cd, Cr,
Ni, Pb, and Zn by these vegetables is also discussed.},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
Trace element contaminants in kitchen garden soils can contribute
to human exposure through the consumption of homegrown vegetables.
In urban areas, these soils can be contaminated to various degrees
by trace element (TE). They are characterized by a great variability
in their physicochemical parameters due to the high anthropization
level, the wide variety and combination of disturbance sources, aswell
as the diversity of cultivation practices and the large range of
contamination levels. Pollutants can be taken up by vegetables cultivated
in these soils and be concentrated in their edible parts. In this
review, the behavior of vegetables cultivated in contaminated kitchen
gardens is assessed through six examples of the most widely cultivated
vegetables (lettuce, tomato, bean, carrot, radish, potato). The role
of soil parameters that could influence the uptake of As, Cd, Cr,
Ni, Pb, and Zn by these vegetables is also discussed. |
2020Book ER4 Auteurs : Pelfrêne, Aurelie; Bidar, Géraldine; Détriché, Sébastien; Waterlot, Christophe; Pruvot, Christelle; Douay, Francis Spécificités des potagers en contexte (péri)urbain au lourd passé industriel 2020, (OS). @book{Pelfrene2020c,
title = {Spécificités des potagers en contexte (péri)urbain au lourd passé industriel},
author = {Aurelie Pelfrêne and Géraldine Bidar and Sébastien Détriché and Christophe Waterlot and Christelle Pruvot and Francis Douay},
year = {2020},
date = {2020-01-01},
booktitle = {in "Les sols urbains sont-ils cultivables ?" (Editions Quae, Collection Matière à débattres & décider)},
note = {OS},
keywords = {ER4},
pubstate = {published},
tppubtype = {book}
}
|
2019Journal Article ER4 Auteurs : Bidar, Géraldine; Pelfrêne, Aurélie; Louvel, Brice; Janus, Adeline; Douay, Francis Influence of amendments on metal environmental and toxicological availability in highly contaminated brownfield and agricultural soils In: Environmental Science and Pollution Research, vol. 26, pp. 33086–33108, 2019, (ACL). Abstract @article{Bidar2019,
title = {Influence of amendments on metal environmental and toxicological availability in highly contaminated brownfield and agricultural soils},
author = {Géraldine Bidar and Aurélie Pelfrêne and Brice Louvel and Adeline Janus and Francis Douay},
year = {2019},
date = {2019-01-01},
journal = {Environmental Science and Pollution Research},
volume = {26},
pages = {33086–33108},
abstract = {The immobilizing effects of wood biochar (BW2%) and iron grit (Z1%)
applied alone or in combination (BW2% + Z1%) to agricultural (M750)
and brownfield (MAZ) soils highly contaminated by metals were assessed
in a greenhouse experiment. The results showed that Z1% and BW2%
+ Z1% were the most efficient amendments to reduce Cd, Cu, Pb, and
Zn mobility, environmental availability, and phytoavailability in
the M750 soil. The oxidation of Z1% allowed part of the Cu and Zn
pools present in exchangeable or carbonate-bound forms (labile fraction)
to complex in less mobile forms. In this soil, the metal chemical
extractions (0.01 M CaCl2 and 0.05 M EDTA) and the DGT (diffusive
gradient in thin films) devices to assess metal in soil solution
and soil pore water (SPW) also highlighted the immobilizing characteristic
of Z1%. In most cases, the addition of BW2% to Z1% (BW2% + Z1%) did
not improve this effect, except for the dissolved Pb and Zn concentrations
in the M750 soil solution. It was also observed that Cd, Pb, and
Zn passed throughout DGT mimicking the biological cell membrane were
reduced by all amendments of the M750 soil corroborating metal concentrations
measured in rye grass shoots. In the MAZ soil, metals were less available
as shown by their low extractability rate, low capacity of metal
resupply from the solid phase to pore water, and low phytoavailability.
The poor metal availability could be explained by the high levels
of carbonate and organic matter contents in this soil. Nevertheless,
a decrease of the Cu environmental availability and the Cu concentrations
in rye grass shoots grown on the MAZ soil was also observed in the
soil amended with Z1% alone or in combination with BW2%. From a health
point of view, the most effective amendment to reduce human exposure
through ingestion of soil particles for the M750 and MAZ soils was
BW2% for Cd and BW2% + Z1% for Pb. However, the presence of rye grass
minimized the amendments’ beneficial effects.},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
The immobilizing effects of wood biochar (BW2%) and iron grit (Z1%)
applied alone or in combination (BW2% + Z1%) to agricultural (M750)
and brownfield (MAZ) soils highly contaminated by metals were assessed
in a greenhouse experiment. The results showed that Z1% and BW2%
+ Z1% were the most efficient amendments to reduce Cd, Cu, Pb, and
Zn mobility, environmental availability, and phytoavailability in
the M750 soil. The oxidation of Z1% allowed part of the Cu and Zn
pools present in exchangeable or carbonate-bound forms (labile fraction)
to complex in less mobile forms. In this soil, the metal chemical
extractions (0.01 M CaCl2 and 0.05 M EDTA) and the DGT (diffusive
gradient in thin films) devices to assess metal in soil solution
and soil pore water (SPW) also highlighted the immobilizing characteristic
of Z1%. In most cases, the addition of BW2% to Z1% (BW2% + Z1%) did
not improve this effect, except for the dissolved Pb and Zn concentrations
in the M750 soil solution. It was also observed that Cd, Pb, and
Zn passed throughout DGT mimicking the biological cell membrane were
reduced by all amendments of the M750 soil corroborating metal concentrations
measured in rye grass shoots. In the MAZ soil, metals were less available
as shown by their low extractability rate, low capacity of metal
resupply from the solid phase to pore water, and low phytoavailability.
The poor metal availability could be explained by the high levels
of carbonate and organic matter contents in this soil. Nevertheless,
a decrease of the Cu environmental availability and the Cu concentrations
in rye grass shoots grown on the MAZ soil was also observed in the
soil amended with Z1% alone or in combination with BW2%. From a health
point of view, the most effective amendment to reduce human exposure
through ingestion of soil particles for the M750 and MAZ soils was
BW2% for Cd and BW2% + Z1% for Pb. However, the presence of rye grass
minimized the amendments’ beneficial effects. |
2019Journal Article ER4 Auteurs : Leclercq-Dransart, Julie; Demuynck, Sylvain; Bidar, Géraldine; Douay, Francis; Grumiaux, Fabien; Louvel, Brice; Pernin, Céline; Leprêtre, Alain Does adding fly ash to metal-contaminated soils play a role in soil functionality regarding metal availability, litter quality, microbial activity and the community structure of Diptera larvae? In: Applied Soil Ecology, vol. 138, pp. 99-111, 2019, (ACL). Abstract @article{Leclercq-Dransart2019,
title = {Does adding fly ash to metal-contaminated soils play a role in soil functionality regarding metal availability, litter quality, microbial activity and the community structure of Diptera larvae?},
author = {Julie Leclercq-Dransart and Sylvain Demuynck and Géraldine Bidar and Francis Douay and Fabien Grumiaux and Brice Louvel and Céline Pernin and Alain Leprêtre},
year = {2019},
date = {2019-01-01},
journal = {Applied Soil Ecology},
volume = {138},
pages = {99-111},
abstract = {This study aimed at evaluating the impact of the use of fly ash-aided
phytostabilisation as a method to manage highly metal-contaminated
soils on soil functionality taking into account the soil and the
litter qualities, the Diptera larvae communities and the microbial
activity. To reach this goal, 70 parameters were studied. The main
results showed that the two studied fly ashes Soproline® and Sodeline®
had a positive influence on soil characteristics especially the availability
of metals, nearly 14 years after amendment. Regarding biological
parameters, no positive or negative effects were found by adding
fly ashes to the soil concerning soil basal respiration and urease
activity. The fungal activity was even enhanced. In the same way,
the fly ashes had no negative effect on the Diptera larvae community
and a greater richness of larvae was even found in amended soils.
Thus, this study confirmed that aided-phytostabilisation using these
fly ashes should be an advantageous technique to manage metal-polluted
soils and to recycle industrial wastes.},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
This study aimed at evaluating the impact of the use of fly ash-aided
phytostabilisation as a method to manage highly metal-contaminated
soils on soil functionality taking into account the soil and the
litter qualities, the Diptera larvae communities and the microbial
activity. To reach this goal, 70 parameters were studied. The main
results showed that the two studied fly ashes Soproline® and Sodeline®
had a positive influence on soil characteristics especially the availability
of metals, nearly 14 years after amendment. Regarding biological
parameters, no positive or negative effects were found by adding
fly ashes to the soil concerning soil basal respiration and urease
activity. The fungal activity was even enhanced. In the same way,
the fly ashes had no negative effect on the Diptera larvae community
and a greater richness of larvae was even found in amended soils.
Thus, this study confirmed that aided-phytostabilisation using these
fly ashes should be an advantageous technique to manage metal-polluted
soils and to recycle industrial wastes. |
2019Conference ER4 Auteurs : Bidar, Géraldine; Louvel, Brice; Janus, Adeline; Blarel, Jacques; Lemoine, Guillaume; Douay, Francis Evaluation in situ des effets d’amendements sur le comportement du blé cultivé sur une parcelle agricole contaminée par les activités passées d’une fonderie de plomb 4ème Rencontres nationales de la Recherche sur les sites et sols pollués, Le Beffroi de Montrouge, 26-27 novembre 2019, Paris, 2019, (ACTN). @conference{Bidar2019b,
title = {Evaluation in situ des effets d’amendements sur le comportement du blé cultivé sur une parcelle agricole contaminée par les activités passées d’une fonderie de plomb},
author = {Géraldine Bidar and Brice Louvel and Adeline Janus and Jacques Blarel and Guillaume Lemoine and Francis Douay},
year = {2019},
date = {2019-01-01},
booktitle = {4ème Rencontres nationales de la Recherche sur les sites et sols pollués, Le Beffroi de Montrouge, 26-27 novembre 2019, Paris},
note = {ACTN},
keywords = {ER4},
pubstate = {published},
tppubtype = {conference}
}
|
2019Conference ER4 Auteurs : Bidar, Géraldine; Louvel, Brice; Janus, Adeline; Blarel, Jacques; Lemoine, Guillaume; Douay, Francis In situ assessment of soil amendment effects on hemp behavior in soils highly contaminated by past smelter activities Intersol’2019, International Conference-Exhibition on Soils, Sediments and Water, 26-28 mars 2019, Lille, 2019, (ACTN). @conference{Bidar2019a,
title = {In situ assessment of soil amendment effects on hemp behavior in soils highly contaminated by past smelter activities},
author = {Géraldine Bidar and Brice Louvel and Adeline Janus and Jacques Blarel and Guillaume Lemoine and Francis Douay},
year = {2019},
date = {2019-01-01},
booktitle = {Intersol’2019, International Conference-Exhibition on Soils, Sediments and Water, 26-28 mars 2019, Lille},
note = {ACTN},
keywords = {ER4},
pubstate = {published},
tppubtype = {conference}
}
|
2019Conference ER4 Auteurs : Louvel, Brice; Lemoine, Guillaume; Détriché, Sébastien; Bidar, Géraldine; Janus, Adeline; Douay, Francis Evaluation in situ de modes de gestion appliqués sur une friche multicontaminée de la carbochimie 4ème Rencontres nationales de la Recherche sur les sites et sols pollués, Le Beffroi de Montrouge, 26-27 novembre 2019, Paris, 2019, (ACTN). Abstract @conference{Louvel2019c,
title = {Evaluation in situ de modes de gestion appliqués sur une friche multicontaminée de la carbochimie},
author = {Brice Louvel and Guillaume Lemoine and Sébastien Détriché and Géraldine Bidar and Adeline Janus and Francis Douay},
year = {2019},
date = {2019-01-01},
booktitle = {4ème Rencontres nationales de la Recherche sur les sites et sols pollués, Le Beffroi de Montrouge, 26-27 novembre 2019, Paris},
abstract = {La reconquête des friches industrielles présente des enjeux environnementaux
et sanitaires d’envergure. Dans cet objectif, les phytotechnologies
sont présentées dans la littérature comme un mode de gestion innovant,
transitoire ou pérenne, et limitant la dispersion des polluants en
protégeant les sols de l’érosion. Elles peuvent réduire la disponibilité
des polluants. Néanmoins, ces techniques manquent encore de recul
opérationnel [1]. Le projet MisChar, soutenu par l’ADEME, vise à
apporter un regard scientifique, technique et économique sur différents
modes de gestion appliqués sur des sols multicontaminés par des activités
industrielles passées. Une expérimentation a été mise en place avec
pour objectif d’étudier les effets de modes de gestion basés sur
l’utilisation d’un amendement des sols, l’installation de communautés
végétales et des pratiques usuelles d’entretien des espaces verts.
Elle concerne une parcelle située dans l’ancien Bassin minier du
Nord – Pas de Calais sur laquelle ont été déposés des matériaux multicontaminés
issus de la carbochimie (usines de Mazingarbe). Au printemps 2018,
20 placettes d’une surface de 20 m² ont été définies. Le sol de 10
de ces placettes a été amendé au moyen d’un mélange de biochar de
miscanthus et de compost de déchets verts. Les 10 autres placettes
ont été utilisées comme témoin. A chacune de ces placettes correspond
un type d’ensemencement particulier et un mode de gestion distinct.
Ainsi, diverses essences végétales ont été semées. Il s’agit (1)
d’un mélange d’espèces classiquement mis en oeuvre sur les espaces
verts (ray-grass anglais, fétuque rouge gazonnante, fétuque rouge
traçante et pâturin des prés), (2) d’un mélange d’espèces sélectionnées
pour leurs comportements présumés vis-à-vis des polluants (stabilisation
des polluants métalliques, rhizo/phytodégradation de certains polluants
organiques (ray-grass anglais, agrostide stolonifère, fétuque rouge,
trèfle blanc), et des mêmes espèces en implantation monospécifique
avec (3) un ray-grass, (4) une agrostis stolonifère, (5) un trèfle
blanc, et (6) une fétuque rouge. Une septième modalité correspond
à l’installation d’une végétation spontanée. Aux espèces implantées
en mélange et à la végétation spontanée, correspondent deux modes
de gestion (tonte ou pas du couvert végétal). Durant les trois années
d’expérimentation seront étudiés le comportement des polluants des
sols, les effets des modes de gestion sur les communautés végétales
et d’une façon globale, sur la fonctionnalité des sols.},
note = {ACTN},
keywords = {ER4},
pubstate = {published},
tppubtype = {conference}
}
La reconquête des friches industrielles présente des enjeux environnementaux
et sanitaires d’envergure. Dans cet objectif, les phytotechnologies
sont présentées dans la littérature comme un mode de gestion innovant,
transitoire ou pérenne, et limitant la dispersion des polluants en
protégeant les sols de l’érosion. Elles peuvent réduire la disponibilité
des polluants. Néanmoins, ces techniques manquent encore de recul
opérationnel [1]. Le projet MisChar, soutenu par l’ADEME, vise à
apporter un regard scientifique, technique et économique sur différents
modes de gestion appliqués sur des sols multicontaminés par des activités
industrielles passées. Une expérimentation a été mise en place avec
pour objectif d’étudier les effets de modes de gestion basés sur
l’utilisation d’un amendement des sols, l’installation de communautés
végétales et des pratiques usuelles d’entretien des espaces verts.
Elle concerne une parcelle située dans l’ancien Bassin minier du
Nord – Pas de Calais sur laquelle ont été déposés des matériaux multicontaminés
issus de la carbochimie (usines de Mazingarbe). Au printemps 2018,
20 placettes d’une surface de 20 m² ont été définies. Le sol de 10
de ces placettes a été amendé au moyen d’un mélange de biochar de
miscanthus et de compost de déchets verts. Les 10 autres placettes
ont été utilisées comme témoin. A chacune de ces placettes correspond
un type d’ensemencement particulier et un mode de gestion distinct.
Ainsi, diverses essences végétales ont été semées. Il s’agit (1)
d’un mélange d’espèces classiquement mis en oeuvre sur les espaces
verts (ray-grass anglais, fétuque rouge gazonnante, fétuque rouge
traçante et pâturin des prés), (2) d’un mélange d’espèces sélectionnées
pour leurs comportements présumés vis-à-vis des polluants (stabilisation
des polluants métalliques, rhizo/phytodégradation de certains polluants
organiques (ray-grass anglais, agrostide stolonifère, fétuque rouge,
trèfle blanc), et des mêmes espèces en implantation monospécifique
avec (3) un ray-grass, (4) une agrostis stolonifère, (5) un trèfle
blanc, et (6) une fétuque rouge. Une septième modalité correspond
à l’installation d’une végétation spontanée. Aux espèces implantées
en mélange et à la végétation spontanée, correspondent deux modes
de gestion (tonte ou pas du couvert végétal). Durant les trois années
d’expérimentation seront étudiés le comportement des polluants des
sols, les effets des modes de gestion sur les communautés végétales
et d’une façon globale, sur la fonctionnalité des sols. |
2019Journal Article ER4 Auteurs : Leclercq-Dransart, Julie; Demuynck, Sylvain; Waterlot, Christophe; Bidar, Géraldine; Sahmer, Karin; Pernin, Céline; Deram, A; Leprêtre, Alain; Douay, Francis Distribution of metals and cell wall compounds in leaf parts of three tree species suitable for the phytomanagement of heavy metal–contaminated soils In: Water Air and Soil Pollution, vol. 230, no. 237, pp. 1-16, 2019, (ACL). Abstract @article{Leclercq-Dransar2019,
title = {Distribution of metals and cell wall compounds in leaf parts of three tree species suitable for the phytomanagement of heavy metal–contaminated soils},
author = {Julie Leclercq-Dransart and Sylvain Demuynck and Christophe Waterlot and Géraldine Bidar and Karin Sahmer and Céline Pernin and A Deram and Alain Leprêtre and Francis Douay},
year = {2019},
date = {2019-01-01},
journal = {Water Air and Soil Pollution},
volume = {230},
number = {237},
pages = {1-16},
abstract = {Phytomanagement used on soils contaminated with metals aims to stabilize
them in the soil. It generally uses less demanding tree species such
as maple, poplar, and black locust. However, it is important to consider
the rate of accumulation of metals in the leaves as well as their
location (leaf blade/petiole) together with the contents of cell
wall compounds (hemicelluloses, cellulose, lignin). These two aspects
are likely not only to have repercussions on the decomposition of
litter but also to lead to a possible transfer ofmetal contamination
into the food chain via soil decomposers/detritivorous. A successful
phytoremediation is therefore the result of compromise: no tree species
can meet all these criteria. The results obtained show that poplar
is not recommended due to a high accumulation of Cd and Zn. The most
appropriate species among our 3 studied species, which seem the most
suitable in terms of remediation of metal polluted soils, could be
the black locust and the maple which are less susceptible to contribute
to the transfer of exogenous metals such as Cd to the trophic chain.
However, maple strongly accumulates Pb in the leaf blade and it is
susceptible to degrade quickly due to its high hemicelluloses and
cellulose contents and low lignin content. The black locust accumulates
metals mainly in the petiole (little consumed by detritivorous).
However, its exotic character and high lignin content may limit the
interest of its use.},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
Phytomanagement used on soils contaminated with metals aims to stabilize
them in the soil. It generally uses less demanding tree species such
as maple, poplar, and black locust. However, it is important to consider
the rate of accumulation of metals in the leaves as well as their
location (leaf blade/petiole) together with the contents of cell
wall compounds (hemicelluloses, cellulose, lignin). These two aspects
are likely not only to have repercussions on the decomposition of
litter but also to lead to a possible transfer ofmetal contamination
into the food chain via soil decomposers/detritivorous. A successful
phytoremediation is therefore the result of compromise: no tree species
can meet all these criteria. The results obtained show that poplar
is not recommended due to a high accumulation of Cd and Zn. The most
appropriate species among our 3 studied species, which seem the most
suitable in terms of remediation of metal polluted soils, could be
the black locust and the maple which are less susceptible to contribute
to the transfer of exogenous metals such as Cd to the trophic chain.
However, maple strongly accumulates Pb in the leaf blade and it is
susceptible to degrade quickly due to its high hemicelluloses and
cellulose contents and low lignin content. The black locust accumulates
metals mainly in the petiole (little consumed by detritivorous).
However, its exotic character and high lignin content may limit the
interest of its use. |
2018Conference ER4 Auteurs : Janus, Adeline; Pelfrêne, Aurélie; Bidar, Géraldine; Louvel, Brice; Douay, Francis Influence of two amendments on phyto- and sanitary availability of metals in highly contaminated soils: A greenhouse study International Conference Contaminated Sites 2018, 8-10 October 2018, Banská Bystrica (Slovak Republic), 2018, (COM). Abstract @conference{Janus2018,
title = {Influence of two amendments on phyto- and sanitary availability of metals in highly contaminated soils: A greenhouse study},
author = {Adeline Janus and Aurélie Pelfrêne and Géraldine Bidar and Brice Louvel and Francis Douay},
year = {2018},
date = {2018-01-01},
booktitle = {International Conference Contaminated Sites 2018, 8-10 October 2018, Banská Bystrica (Slovak Republic)},
pages = {101},
abstract = {Soil is an essential and non-renewable resource which can perform
a high number of economic, social and environmental functions as
biomass production, source of raw materials or protection of humans
and environment (Blum, 2005). However, the soil functionality becomes
increasingly compromised due to contaminations caused by human activities.
In 2006 and in 39 countries, the European Environmental Agency inventoried
approximately 3 million of sites where pollutant activities occurred
with more than 1 .8 million potentially contaminated sites (CGDD
2013). In 2012, the most frequently identified contaminants were
metals (35 %), hydrocarbons (24 %) and polycyclic aromatic hydrocarbons
(11 %). Until recently, the most common remediation technique was
the excavation of contaminated soil and its disposal as landfill.
However, this kind of method is considered inappropriate because
it generates considerable disturbances, is expensive and economically
unfeasible on a large scale . Thus, other remediation techniques
(ex and in situ) have been developed to overcome these disadvantages
. Among them, a technique consists in adding inorganic or organic
amendments to the contaminated soils in order to decrease the mobility
and bioavailability of pollutants in soils (Kumpiene et al., 2008;
Vangronsveld et al., 2009; Bolan et al., 2014; Nejad et al., 2017)
. The most often used amendments are phosphate compounds, liming
materials, metal oxides and biochars, used alone or in combination
(Waterlot et al., 2017; Lahori et al., 2017; Oustrière et al., 2017).
The goal of the present work consists in evaluating the ability of
two amendments (woody biochar and iron grit, used alone or in combination)
to immobilize Cd, Cu, Pb, and Zn in contaminated soils under greenhouse
conditions},
note = {COM},
keywords = {ER4},
pubstate = {published},
tppubtype = {conference}
}
Soil is an essential and non-renewable resource which can perform
a high number of economic, social and environmental functions as
biomass production, source of raw materials or protection of humans
and environment (Blum, 2005). However, the soil functionality becomes
increasingly compromised due to contaminations caused by human activities.
In 2006 and in 39 countries, the European Environmental Agency inventoried
approximately 3 million of sites where pollutant activities occurred
with more than 1 .8 million potentially contaminated sites (CGDD
2013). In 2012, the most frequently identified contaminants were
metals (35 %), hydrocarbons (24 %) and polycyclic aromatic hydrocarbons
(11 %). Until recently, the most common remediation technique was
the excavation of contaminated soil and its disposal as landfill.
However, this kind of method is considered inappropriate because
it generates considerable disturbances, is expensive and economically
unfeasible on a large scale . Thus, other remediation techniques
(ex and in situ) have been developed to overcome these disadvantages
. Among them, a technique consists in adding inorganic or organic
amendments to the contaminated soils in order to decrease the mobility
and bioavailability of pollutants in soils (Kumpiene et al., 2008;
Vangronsveld et al., 2009; Bolan et al., 2014; Nejad et al., 2017)
. The most often used amendments are phosphate compounds, liming
materials, metal oxides and biochars, used alone or in combination
(Waterlot et al., 2017; Lahori et al., 2017; Oustrière et al., 2017).
The goal of the present work consists in evaluating the ability of
two amendments (woody biochar and iron grit, used alone or in combination)
to immobilize Cd, Cu, Pb, and Zn in contaminated soils under greenhouse
conditions |
2018Conference ER4 Auteurs : Mench, Michel; Oustrière, Nadège; Marchand, Lilian; Dellise, M; Matin, S; Fichou, A; Lafargue, T; Darroman, A; Lacalle, R G; Burges, A; Castagneyrol, Bastien; Jouveau, Séverin; Sæbø, Arne; Persson, Tomas; Hanslin, Hans-Martin; Høglind, Mats; Edvardsen, Marte-Lund; Sørlie, Hanne; Schröder, Peter; Obermeier, Michael; Szulc, Wieslaw; Rutkowska, Beata; Vangronsveld, Jaco; Witters, Nele; Beckers, Bram; Rineau, François; Daniels, S; Olcay, Hakan; Malina, Robert; Millán, Rocio; Schmid, Thomas; Sierra, María-José; Poschenrieder, Charlotte; Marmiroli, Nelson; Maestri, Elena; Reggiani, R; López-Gonzalez, J -A; Bidar, Géraldine; Douay, Francis Intensify production, transform biomass to energy and novel goods and protect soils in Europe (INTENSE): Progress in year 2 The 15th International Phytotechnology Conference, 1-5 October 2018, University of Novi Sad (Serbia), 2018, (ACTI). Abstract @conference{Mench2018,
title = {Intensify production, transform biomass to energy and novel goods and protect soils in Europe (INTENSE): Progress in year 2},
author = {Michel Mench and Nadège Oustrière and Lilian Marchand and M Dellise and S Matin and A Fichou and T Lafargue and A Darroman and R G Lacalle and A Burges and Bastien Castagneyrol and Séverin Jouveau and Arne Sæbø and Tomas Persson and Hans-Martin Hanslin and Mats Høglind and Marte-Lund Edvardsen and Hanne Sørlie and Peter Schröder and Michael Obermeier and Wieslaw Szulc and Beata Rutkowska and Jaco Vangronsveld and Nele Witters and Bram Beckers and François Rineau and S Daniels and Hakan Olcay and Robert Malina and Rocio Millán and Thomas Schmid and María-José Sierra and Charlotte Poschenrieder and Nelson Marmiroli and Elena Maestri and R Reggiani and J -A López-Gonzalez and Géraldine Bidar and Francis Douay},
year = {2018},
date = {2018-01-01},
booktitle = {The 15th International Phytotechnology Conference, 1-5 October 2018, University of Novi Sad (Serbia)},
pages = {130},
abstract = {The European INTENSE project is responding to three “Great Challenges”:
global food security, use of renewable raw materials and production
of energy from biomass. Its contributes to reconvert poor, abandoned
and polluted lands, e.g. grassland, set aside land, brownfields,
and other marginal lands, into high, sustainable crop production.
INTENSE sites are located throughout Europe from Spain in the south
up to Norway in the north. Regarding precision agriculture, modeling
tools and soil amendments, field plots are assessed using unmanned
aerial vehicles and data crossed with those from crop production
and soil microbial communities. This provides information on field
heterogeneity to adapt soil management, seeding, fertilizing, and
fungicide and herbicide application, allowing site-specific farming.
At the Martlhof farm, Germany, increase in photosynthetic activity
of barley was observed after incorporation of digested pig manure
(solid fraction alone and with biochar) and compost although N uptake
was similar. At Buendia and Casasana, Spain, barley plots with mineral
N combined with compost pellets and biochar showed increased GNDVI
(i.e. (NIR – green)/(NIR + green). Field data and image spectroscopy
evidenced differences across plots, cultivars, plant performance
and health. At Polish sites, compost combined with mineral N increased
barley and maize yields. Suitable production systems are developed
and implemented for land amelioration in complex degradation situations.
At Martlhof, chestnut wood chips are pyrolysed to produce and use
biochar. Extensive livestock farming is transformed to ecological
intensive farming including livestock with monogastric animals, intercropping
(Fabaceae), agroforestry, terraforming, and increased biodiversity
(landscape ecology). Soil nutrients and biological functionality
(FDA hydrolysis, community-level physiological profiling, and microbial
DNA extractions) are analyzed at the beginning and after each growing
season, showing high nutrient turnover, and increase in soil N and
P contents. Organic amendments more influence overall microbial activity
than functional diversity. Overall, the more organic matter, the
higher the microbial activity. At French sites, long-term phytomanagement
of contaminated soils with high yielding crops and short rotation
coppices, combined with soil amendments, improved soil fertility,
C sequestration, can stimulate microbial activity, and limited pollutant
linkages. Weed control, reduced invasive vegetation, pest control,
effect of soil mycorrhizae on nutrient cycling, and shelter belts
are investigated. At Spanish sites, farming systems can be adapted
by limiting wind erosion and water runoff, shaping stony fields,
tree planting, soil amendment, winter crops and intercropping. At
the farm level, environmental education, direct marketing, and (bio)energy
production can add values},
note = {ACTI},
keywords = {ER4},
pubstate = {published},
tppubtype = {conference}
}
The European INTENSE project is responding to three “Great Challenges”:
global food security, use of renewable raw materials and production
of energy from biomass. Its contributes to reconvert poor, abandoned
and polluted lands, e.g. grassland, set aside land, brownfields,
and other marginal lands, into high, sustainable crop production.
INTENSE sites are located throughout Europe from Spain in the south
up to Norway in the north. Regarding precision agriculture, modeling
tools and soil amendments, field plots are assessed using unmanned
aerial vehicles and data crossed with those from crop production
and soil microbial communities. This provides information on field
heterogeneity to adapt soil management, seeding, fertilizing, and
fungicide and herbicide application, allowing site-specific farming.
At the Martlhof farm, Germany, increase in photosynthetic activity
of barley was observed after incorporation of digested pig manure
(solid fraction alone and with biochar) and compost although N uptake
was similar. At Buendia and Casasana, Spain, barley plots with mineral
N combined with compost pellets and biochar showed increased GNDVI
(i.e. (NIR – green)/(NIR + green). Field data and image spectroscopy
evidenced differences across plots, cultivars, plant performance
and health. At Polish sites, compost combined with mineral N increased
barley and maize yields. Suitable production systems are developed
and implemented for land amelioration in complex degradation situations.
At Martlhof, chestnut wood chips are pyrolysed to produce and use
biochar. Extensive livestock farming is transformed to ecological
intensive farming including livestock with monogastric animals, intercropping
(Fabaceae), agroforestry, terraforming, and increased biodiversity
(landscape ecology). Soil nutrients and biological functionality
(FDA hydrolysis, community-level physiological profiling, and microbial
DNA extractions) are analyzed at the beginning and after each growing
season, showing high nutrient turnover, and increase in soil N and
P contents. Organic amendments more influence overall microbial activity
than functional diversity. Overall, the more organic matter, the
higher the microbial activity. At French sites, long-term phytomanagement
of contaminated soils with high yielding crops and short rotation
coppices, combined with soil amendments, improved soil fertility,
C sequestration, can stimulate microbial activity, and limited pollutant
linkages. Weed control, reduced invasive vegetation, pest control,
effect of soil mycorrhizae on nutrient cycling, and shelter belts
are investigated. At Spanish sites, farming systems can be adapted
by limiting wind erosion and water runoff, shaping stony fields,
tree planting, soil amendment, winter crops and intercropping. At
the farm level, environmental education, direct marketing, and (bio)energy
production can add values |
2017Journal Article ER4 Auteurs : Labidi, Sonia; Firmin, Stéphane; Verdin, Anthony; Bidar, Géraldine; Laruelle, Frédéric; Douay, Francis; Shirali, Pirouz; Fontaine, Joël; Lounès-Hadj-Sahraoui, Anissa Nature of fly ash amendments differently influences oxidative stress alleviation in four forest tree species and metal trace element phytostabilization in aged contaminated soil: A long-term field experiment In: Ecotoxicology and Environmental Safety, vol. 138, pp. 190-198, 2017, (ACL). Abstract @article{Labidi2017,
title = {Nature of fly ash amendments differently influences oxidative stress alleviation in four forest tree species and metal trace element phytostabilization in aged contaminated soil: A long-term field experiment},
author = {Sonia Labidi and Stéphane Firmin and Anthony Verdin and Géraldine Bidar and Frédéric Laruelle and Francis Douay and Pirouz Shirali and Joël Fontaine and Anissa Lounès-Hadj-Sahraoui},
year = {2017},
date = {2017-01-01},
journal = {Ecotoxicology and Environmental Safety},
volume = {138},
pages = {190-198},
abstract = {Aided phytostabilization using coal fly ashes (cfas) is an interesting technique to clean-up polluted soils and valorizing industrial wastes. in this context, our work aims to study the effect of two cfas: silico-aluminous (cfa1) and sulfo-calcic (cfa2) ones, 10 years after their addition, on the phytostabilization of a highly cd (cadmium), pb (lead) and zn (zinc) contaminated agricultural soil, with four forest tree species: robinia pseudoacacia, alms glutinosa, acer pseudoplatanus and salix alba. to assess the effect of cfas on trees, leaf fatty acid composition, malondialdehyde (mda), oxidized and reduced glutathione contents ratio (gssg: gsh), 8hydroxy-2'-deoxyguanosine (8-ohdg), peroxidase (po) and superoxide dismutase (sod) activities were examined. our results showed that cfa amendments decreased the cac1(2-)extractable fraction of cd and zn from the soil. however, no significant effect was observed on metal trace element (mte) concentrations in leaves. fatty acid percentages were only affected by the addition of sulfo-calcic cfa. the most affected species were a. glutinosa and r. pseudoacacia in which c16:0, c18:0 and c18:2 percentages increased significantly whereas the c18:3 decreased. the addition of sulfo-calcic cfa induced the antioxidant systems response in tree leaves. an increase of sod and pod activities in leaves of trees planted on the cfa2-amended plot was recorded. conversely, silico-aluminous cfa generated a reduction of lipid and dna oxidation associated with the absence or low induction of anti-oxidative processes. our study evidenced oxidative stress alleviation in tree leaves due to cfa amendments. mte mobility in contaminated soil and their accumulation in leaves differed with the nature of cfa amendments and the selected tree species.},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
Aided phytostabilization using coal fly ashes (cfas) is an interesting technique to clean-up polluted soils and valorizing industrial wastes. in this context, our work aims to study the effect of two cfas: silico-aluminous (cfa1) and sulfo-calcic (cfa2) ones, 10 years after their addition, on the phytostabilization of a highly cd (cadmium), pb (lead) and zn (zinc) contaminated agricultural soil, with four forest tree species: robinia pseudoacacia, alms glutinosa, acer pseudoplatanus and salix alba. to assess the effect of cfas on trees, leaf fatty acid composition, malondialdehyde (mda), oxidized and reduced glutathione contents ratio (gssg: gsh), 8hydroxy-2'-deoxyguanosine (8-ohdg), peroxidase (po) and superoxide dismutase (sod) activities were examined. our results showed that cfa amendments decreased the cac1(2-)extractable fraction of cd and zn from the soil. however, no significant effect was observed on metal trace element (mte) concentrations in leaves. fatty acid percentages were only affected by the addition of sulfo-calcic cfa. the most affected species were a. glutinosa and r. pseudoacacia in which c16:0, c18:0 and c18:2 percentages increased significantly whereas the c18:3 decreased. the addition of sulfo-calcic cfa induced the antioxidant systems response in tree leaves. an increase of sod and pod activities in leaves of trees planted on the cfa2-amended plot was recorded. conversely, silico-aluminous cfa generated a reduction of lipid and dna oxidation associated with the absence or low induction of anti-oxidative processes. our study evidenced oxidative stress alleviation in tree leaves due to cfa amendments. mte mobility in contaminated soil and their accumulation in leaves differed with the nature of cfa amendments and the selected tree species. |
2016Journal Article ER4 Auteurs : Bidar, Géraldine; Waterlot, Christophe; Verdin, Anthony; Proix, Nicolas; Courcot, Dominique; Détriché, Sébastien; Fourrier, Hervé; Richard, Antoine; Douay, Francis Sustainability of an in situ aided phytostabilisation on highly contaminated soils using fly ashes: Effects on the vertical distribution of physicochemical parameters and trace elements In: Journal of Environmental Management, vol. 171, pp. 204-216, 2016, (ACL). Abstract @article{Bidar2016,
title = {Sustainability of an in situ aided phytostabilisation on highly contaminated soils using fly ashes: Effects on the vertical distribution of physicochemical parameters and trace elements},
author = {Géraldine Bidar and Christophe Waterlot and Anthony Verdin and Nicolas Proix and Dominique Courcot and Sébastien Détriché and Hervé Fourrier and Antoine Richard and Francis Douay},
year = {2016},
date = {2016-01-01},
journal = {Journal of Environmental Management},
volume = {171},
pages = {204-216},
abstract = {Aided phytostabilisation using trees and fly ashes is a promising technique which has shown its effectiveness in the management of highly metal-contaminated soils. however, this success is generally established based on topsoil physicochemical analysis and short-term experiments. this paper focuses on the long-term effects of the afforestation and twofly ashes (silico-aluminous and sulfo-calcic called fa1 and fa2, respectively) by assessing the integrity of fly ashes 10 years after their incorporation into the soil as well as the vertical distribution of the physicochemical parameters and trace elements (tes) in the amended soils (f1 and f2) in comparison with a non-amended soil (r). ten years after the soil treatment, the particle size distribution analysis between fly ashes and their corresponding masses (fly ash þ soil particles) showed a loss or an agglomeration of finer particles. this evolution matches with the appearance of gypsum (caso4 2h2o) in fa2m instead of anhydrite (caso4), which is the major compound of fa2. this finding corresponds well with the dissolution and the lixiviation of ca, s and p included in fa2 along the f2 soil profile, generating an accumulation of these elements at 30 cm depth. however, no variation of te contaminationwas found between 0 and 25 cm depth in f2 soil except for cd. conversely, cd, pb, zn and hg enrichmentwas observed at 25 cm depth in the f1 soil, whereas no enrichmentwas observed for as. the fly ashes studied, and notably fa2, were able to reduce cd, pb and zn availability in soil and this capacity persists over the time despite their structural and chemical changes.},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
Aided phytostabilisation using trees and fly ashes is a promising technique which has shown its effectiveness in the management of highly metal-contaminated soils. however, this success is generally established based on topsoil physicochemical analysis and short-term experiments. this paper focuses on the long-term effects of the afforestation and twofly ashes (silico-aluminous and sulfo-calcic called fa1 and fa2, respectively) by assessing the integrity of fly ashes 10 years after their incorporation into the soil as well as the vertical distribution of the physicochemical parameters and trace elements (tes) in the amended soils (f1 and f2) in comparison with a non-amended soil (r). ten years after the soil treatment, the particle size distribution analysis between fly ashes and their corresponding masses (fly ash þ soil particles) showed a loss or an agglomeration of finer particles. this evolution matches with the appearance of gypsum (caso4 2h2o) in fa2m instead of anhydrite (caso4), which is the major compound of fa2. this finding corresponds well with the dissolution and the lixiviation of ca, s and p included in fa2 along the f2 soil profile, generating an accumulation of these elements at 30 cm depth. however, no variation of te contaminationwas found between 0 and 25 cm depth in f2 soil except for cd. conversely, cd, pb, zn and hg enrichmentwas observed at 25 cm depth in the f1 soil, whereas no enrichmentwas observed for as. the fly ashes studied, and notably fa2, were able to reduce cd, pb and zn availability in soil and this capacity persists over the time despite their structural and chemical changes. |
2016Journal Article ER4 Auteurs : Waterlot, Christophe; Pruvot, Christelle; Bidar, Géraldine; Fritsch, Clémentine; De-Vaufleury, Annette; Scheifler, Renaud; Douay, Francis Prediction of extractable Cd, Pb and Zn in contaminated woody habitat soils using a change point detection method In: Pedosphere, vol. 26, no. 3, pp. 282-298, 2016, (ACL). Abstract @article{Waterlot2016b,
title = {Prediction of extractable Cd, Pb and Zn in contaminated woody habitat soils using a change point detection method},
author = {Christophe Waterlot and Christelle Pruvot and Géraldine Bidar and Clémentine Fritsch and Annette De-Vaufleury and Renaud Scheifler and Francis Douay},
year = {2016},
date = {2016-01-01},
journal = {Pedosphere},
volume = {26},
number = {3},
pages = {282-298},
abstract = {Accumulation of heavy metals in soils poses a potential risk to plant
production, which is related to availability of the metals in soil.
The phytoavailability of metals is usually evaluated using extracting
solutions such as salts, acids or chelates. The purpose of this study
was to identify the most significant soil parameters that can be
used to predict the concentrations of acetic and citric acid-extractable
cadmium (Cd), lead (Pb) and zinc (Zn) in contaminated woody habitat
topsoils. Multiple linear regression models were established using
two analysis strategies and three sets of variables based on a dataset
of 260 soil samples. The performance of these models was evaluated
using statistical parameters. Cation exchange capacity, CaCO3, organic
matter, assimilated P, free Al oxide, sand and the total metal concentrations
appeared to be the main soil parameters governing the solubility
of Cd, Pb and Zn in acetic and citric acid solutions. The results
strongly suggest that the metal solubility in extracting solutions
is extractable concentration-dependent since models were overall
improved by incorporating a change point. This change point detection
method was a powerful tool for predicting extractable Cd, Pb and
Zn. Suitable predictions of extractable Cd, Pb and Zn concentrations
were obtained, with correlation coefficient (adjusted r) ranging
from 0.80 to 0.99, given the high complexity of the woody habitat
soils studied. Therefore, the predictive models can constitute a
decision-making support tool for managing phytoremediation of contaminated
soils, making recommendations to control the potential bioavailability
of metals. The relationships between acetic and/or citric acid-extractable
concentrations and the concentrations of metals into the aboveground
parts of plants need to be predicted, in order to make their temporal
monitoring easier.},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
Accumulation of heavy metals in soils poses a potential risk to plant
production, which is related to availability of the metals in soil.
The phytoavailability of metals is usually evaluated using extracting
solutions such as salts, acids or chelates. The purpose of this study
was to identify the most significant soil parameters that can be
used to predict the concentrations of acetic and citric acid-extractable
cadmium (Cd), lead (Pb) and zinc (Zn) in contaminated woody habitat
topsoils. Multiple linear regression models were established using
two analysis strategies and three sets of variables based on a dataset
of 260 soil samples. The performance of these models was evaluated
using statistical parameters. Cation exchange capacity, CaCO3, organic
matter, assimilated P, free Al oxide, sand and the total metal concentrations
appeared to be the main soil parameters governing the solubility
of Cd, Pb and Zn in acetic and citric acid solutions. The results
strongly suggest that the metal solubility in extracting solutions
is extractable concentration-dependent since models were overall
improved by incorporating a change point. This change point detection
method was a powerful tool for predicting extractable Cd, Pb and
Zn. Suitable predictions of extractable Cd, Pb and Zn concentrations
were obtained, with correlation coefficient (adjusted r) ranging
from 0.80 to 0.99, given the high complexity of the woody habitat
soils studied. Therefore, the predictive models can constitute a
decision-making support tool for managing phytoremediation of contaminated
soils, making recommendations to control the potential bioavailability
of metals. The relationships between acetic and/or citric acid-extractable
concentrations and the concentrations of metals into the aboveground
parts of plants need to be predicted, in order to make their temporal
monitoring easier. |
2015Journal Article ER4 Auteurs : Nsanganwimana, Florien; Pourrut, Bertrand; Waterlot, Christophe; Louvel, Brice; Bidar, Géraldine; Labidi, Sonia; Fontaine, Joël; Muchembled, Jérôme; Lounès-Hadj-Sahraoui, Anissa; Fourrier, Hervé; Douay, Francis Metal accumulation and shoot yield of Miscanthus × giganteus growing in contaminated agricultural soils: Insights into agronomic practices In: Agriculture, Ecosystems & Environment, vol. 213, pp. 61-71, 2015, (ACL). Abstract @article{Nsanganwimana2015,
title = {Metal accumulation and shoot yield of Miscanthus × giganteus growing in contaminated agricultural soils: Insights into agronomic practices},
author = {Florien Nsanganwimana and Bertrand Pourrut and Christophe Waterlot and Brice Louvel and Géraldine Bidar and Sonia Labidi and Joël Fontaine and Jérôme Muchembled and Anissa Lounès-Hadj-Sahraoui and Hervé Fourrier and Francis Douay},
year = {2015},
date = {2015-01-01},
journal = {Agriculture, Ecosystems & Environment},
volume = {213},
pages = {61-71},
abstract = {The choice of agronomic practices for phytomanagement of metal-contaminated soils is of crucial importance to optimize plant biomass yields and to mitigate both environmental and health risks due to metal exposure. the present study aimed to assess the effects of agronomic practices on shoot yield and on metal (cd, pb, and zn) accumulation in the organs of the energy crop miscanthus (miscanthus × giganteus) during the first three years since the plantation on metal-contaminated agricultural soils. three miscanthus cultivars, hereafter named mis-a, mis-b and mis-i, were planted at low and high density. an inoculum of arbuscular mycorrhizal fungi-amf (glomus lpa val 1) was added during plantation, and nitrogen fertilization was applied during the third growing season. metal accumulation in miscanthus organs was determined during the second growing season, whereas shoot yields and their metal concentrations were determined during both the second and the third growing seasons. based on metal concentrations and bioconcentration factors, the three cultivars mainly accumulated metals in their roots. the shoot yields increased from 3.7 to 10.3 t dw ha−1 in the second growing season to 15.8–23.3 t dw ha−1 in third growing season. there were no or very few significant differences in metal concentrations and shoot yields within treatments comprising the same cultivar. the addition of amf inoculum increased metal (mainly cd and zn) accumulation in miscanthus organs and in the shoot yields and this was more observed in both mis-b and mis-i which presented a higher root mycorrhization level than in mis-a. shoot yields in treatments comprising different cultivars depended not on fertilization but on the interactions between cultivar and planting density, and between cultivar, planting density and amf inoculum. whatever the treatment and the sampling period, pb concentrations did not significantly differ in shoot yields. the interaction between cultivar and planting density resulted in higher cd concentrations in the yields of mis-b planted at low density during the third growing season. zn concentrations increased with fertilization in all treatments, and with the addition of the amf inoculum in mis-b and in mis-i. overall, the results demonstrated that the three cultivars could be potential candidates for coupling phytostabilization and biomass production on metal-contaminated soils.},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
The choice of agronomic practices for phytomanagement of metal-contaminated soils is of crucial importance to optimize plant biomass yields and to mitigate both environmental and health risks due to metal exposure. the present study aimed to assess the effects of agronomic practices on shoot yield and on metal (cd, pb, and zn) accumulation in the organs of the energy crop miscanthus (miscanthus × giganteus) during the first three years since the plantation on metal-contaminated agricultural soils. three miscanthus cultivars, hereafter named mis-a, mis-b and mis-i, were planted at low and high density. an inoculum of arbuscular mycorrhizal fungi-amf (glomus lpa val 1) was added during plantation, and nitrogen fertilization was applied during the third growing season. metal accumulation in miscanthus organs was determined during the second growing season, whereas shoot yields and their metal concentrations were determined during both the second and the third growing seasons. based on metal concentrations and bioconcentration factors, the three cultivars mainly accumulated metals in their roots. the shoot yields increased from 3.7 to 10.3 t dw ha−1 in the second growing season to 15.8–23.3 t dw ha−1 in third growing season. there were no or very few significant differences in metal concentrations and shoot yields within treatments comprising the same cultivar. the addition of amf inoculum increased metal (mainly cd and zn) accumulation in miscanthus organs and in the shoot yields and this was more observed in both mis-b and mis-i which presented a higher root mycorrhization level than in mis-a. shoot yields in treatments comprising different cultivars depended not on fertilization but on the interactions between cultivar and planting density, and between cultivar, planting density and amf inoculum. whatever the treatment and the sampling period, pb concentrations did not significantly differ in shoot yields. the interaction between cultivar and planting density resulted in higher cd concentrations in the yields of mis-b planted at low density during the third growing season. zn concentrations increased with fertilization in all treatments, and with the addition of the amf inoculum in mis-b and in mis-i. overall, the results demonstrated that the three cultivars could be potential candidates for coupling phytostabilization and biomass production on metal-contaminated soils. |
2014Conference ER4 Auteurs : Bidar, Géraldine; Louvel, Brice; Proix, Nicolas; Waterlot, Christophe; Fourrier, Hervé; Richard, Antoine; Douay, Francis Effets à moyen terme d’une phytostabilisation aidée sur la distribution verticale des paramètres physico-chimiques et des éléments traces métalliques dans les sols 3èmes Rencontres nationales de la Recherche sur les sites et sols pollués, ADEME, 18-19 novembre 2014, Paris, 2014, (ACTN). @conference{Bidar2014,
title = {Effets à moyen terme d’une phytostabilisation aidée sur la distribution verticale des paramètres physico-chimiques et des éléments traces métalliques dans les sols},
author = {Géraldine Bidar and Brice Louvel and Nicolas Proix and Christophe Waterlot and Hervé Fourrier and Antoine Richard and Francis Douay},
year = {2014},
date = {2014-01-01},
booktitle = {3èmes Rencontres nationales de la Recherche sur les sites et sols pollués, ADEME, 18-19 novembre 2014, Paris},
note = {ACTN},
keywords = {ER4},
pubstate = {published},
tppubtype = {conference}
}
|
2014Conference ER4 Auteurs : Nsanganwimana, Florien; Pourrut, Bertrand; Waterlot, Christophe; Bidar, Géraldine; Douay, Francis Intérêt de Miscanthus × giganteus pour le phytomanagement de sols agricoles contaminés par des éléments traces métalliques dans le Nord de la France 3èmes Rencontres nationales de la Recherche sur les sites et sols pollués, ADEME, 18-19 novembre 2014, Paris, 2014, (ACTN). @conference{Nsanganwimana2014bb,
title = {Intérêt de Miscanthus × giganteus pour le phytomanagement de sols agricoles contaminés par des éléments traces métalliques dans le Nord de la France},
author = {Florien Nsanganwimana and Bertrand Pourrut and Christophe Waterlot and Géraldine Bidar and Francis Douay},
year = {2014},
date = {2014-01-01},
booktitle = {3èmes Rencontres nationales de la Recherche sur les sites et sols pollués, ADEME, 18-19 novembre 2014, Paris},
note = {ACTN},
keywords = {ER4},
pubstate = {published},
tppubtype = {conference}
}
|
2014Conference ER4 Auteurs : Nsanganwimana, Florien; Waterlot, Christophe; Bidar, Géraldine; Pourrut, Bertrand; Douay, Francis Comportement de Miscanthus cultivé sur des sols fortement contaminés en Cd, Pb et Zn Gestion et requalification durable des sites et sols pollués : Expériences en Nord - Pas de Calais, 25-26 septembre 2014, Villeneuve d’Ascq, 2014, (COM). Abstract @conference{Nsanganwimana2014d,
title = {Comportement de Miscanthus cultivé sur des sols fortement contaminés en Cd, Pb et Zn},
author = {Florien Nsanganwimana and Christophe Waterlot and Géraldine Bidar and Bertrand Pourrut and Francis Douay},
year = {2014},
date = {2014-01-01},
booktitle = {Gestion et requalification durable des sites et sols pollués : Expériences en Nord - Pas de Calais, 25-26 septembre 2014, Villeneuve d’Ascq},
abstract = {Objectifs spécifiques de l’étude §evaluer l’aptitude de m. × giganteus à se developer sur les sols contaminés §etudier l’influence de la culture sur les paramètres physico-chimiques des sols et le comportement de cd, pb et zn §déterminer l’accumulation des etm dans les organes de m. × giganteus selon le gradient de contamination des sols et les pratiques culturales},
note = {COM},
keywords = {ER4},
pubstate = {published},
tppubtype = {conference}
}
Objectifs spécifiques de l’étude §evaluer l’aptitude de m. × giganteus à se developer sur les sols contaminés §etudier l’influence de la culture sur les paramètres physico-chimiques des sols et le comportement de cd, pb et zn §déterminer l’accumulation des etm dans les organes de m. × giganteus selon le gradient de contamination des sols et les pratiques culturales |
2014Conference ER4 Auteurs : Verdin, Anthony; Fontaine, Joël; Firmin, Stéphane; Labidi, Sonia; Bidar, Géraldine; Lopareva-Pohu, Alena; Laruelle, Frédéric; Pourrut, Bertrand; Douay, Francis; Lounès-Hadj-Sahraoui, Anissa; Shirali, Pirouz Phytostabilisation assistée: Influence des amendements minéraux sur le comportement des ETM et la viabilité de la microflore tellurique, des strates herbacée et arborée sur un sol historiquement pollué 3èmes Rencontres nationales de la Recherche sur les sites et sols pollués, ADEME, 18-19 novembre 2014, Paris, 2014, (ACTN). @conference{Verdin2014,
title = {Phytostabilisation assistée: Influence des amendements minéraux sur le comportement des ETM et la viabilité de la microflore tellurique, des strates herbacée et arborée sur un sol historiquement pollué},
author = {Anthony Verdin and Joël Fontaine and Stéphane Firmin and Sonia Labidi and Géraldine Bidar and Alena Lopareva-Pohu and Frédéric Laruelle and Bertrand Pourrut and Francis Douay and Anissa Lounès-Hadj-Sahraoui and Pirouz Shirali},
year = {2014},
date = {2014-01-01},
booktitle = {3èmes Rencontres nationales de la Recherche sur les sites et sols pollués, ADEME, 18-19 novembre 2014, Paris},
note = {ACTN},
keywords = {ER4},
pubstate = {published},
tppubtype = {conference}
}
|
2013Conference ER4 Auteurs : Douay, Francis; Nsanganwimana, Florien; Bidar, Géraldine; Pourrut, Bertrand Apport du phytomanagement dans la gestion de territoires fortement dégradés par les activités humaines : Exemple de Metaleurop (France) Colloque Paysage Transfrontalier; Cœur du Hainaut 2025: Ecriture des paysages d’une regénération industrielle; Faculté d’Architecture et d’Urbanisme de l’Université de Mons, 27-28 mars 2013, Mons (Belgique), 2013, (COM). @conference{Douay2013b,
title = {Apport du phytomanagement dans la gestion de territoires fortement dégradés par les activités humaines : Exemple de Metaleurop (France)},
author = {Francis Douay and Florien Nsanganwimana and Géraldine Bidar and Bertrand Pourrut},
year = {2013},
date = {2013-01-01},
booktitle = {Colloque Paysage Transfrontalier; Cœur du Hainaut 2025: Ecriture des paysages d’une regénération industrielle; Faculté d’Architecture et d’Urbanisme de l’Université de Mons, 27-28 mars 2013, Mons (Belgique)},
note = {COM},
keywords = {ER4},
pubstate = {published},
tppubtype = {conference}
}
|
2013Conference ER4 Auteurs : Douay, Francis; Pourrut, Bertrand; Bidar, Géraldine; Pruvot, Christelle La gestion des sols dégradés par les activités humaines: l'exemple de Metaleurop Au Pays des Racines, Journée de conférences et d’échanges Société Nationale d’Horticulture de France, 31 janvier 2013, Lomme, 2013, (OV). @conference{Douay2013cb,
title = {La gestion des sols dégradés par les activités humaines: l'exemple de Metaleurop},
author = {Francis Douay and Bertrand Pourrut and Géraldine Bidar and Christelle Pruvot},
year = {2013},
date = {2013-01-01},
booktitle = {Au Pays des Racines, Journée de conférences et d’échanges Société Nationale d’Horticulture de France, 31 janvier 2013, Lomme},
note = {OV},
keywords = {ER4},
pubstate = {published},
tppubtype = {conference}
}
|
2013Conference ER4 Auteurs : Pourrut, Bertrand; Bidar, Géraldine; Douay, Francis Les plantes face aux polluants: cas des polluants inorganiques Au Pays des Racines, Journée de conférences et d’échanges Société Nationale d’Horticulture de France, 31 janvier 2013, Lomme, 2013, (OV). @conference{Pourrut2013,
title = {Les plantes face aux polluants: cas des polluants inorganiques},
author = {Bertrand Pourrut and Géraldine Bidar and Francis Douay},
year = {2013},
date = {2013-01-01},
booktitle = {Au Pays des Racines, Journée de conférences et d’échanges Société Nationale d’Horticulture de France, 31 janvier 2013, Lomme},
note = {OV},
keywords = {ER4},
pubstate = {published},
tppubtype = {conference}
}
|
2013Journal Article ER4 Auteurs : Waterlot, Christophe; Bidar, Géraldine; Pelfrêne, Aurélie; Roussel, Hélène; Fourrier, Hervé; Douay, Francis Contamination, fractionation and availability of metals in urban soils in the vicinity of former lead and zinc smelters, France In: Pedosphere, vol. 23, no. 2, pp. 143-159, 2013, (ACL). Abstract @article{Waterlot2013,
title = {Contamination, fractionation and availability of metals in urban soils in the vicinity of former lead and zinc smelters, France},
author = {Christophe Waterlot and Géraldine Bidar and Aurélie Pelfrêne and Hélène Roussel and Hervé Fourrier and Francis Douay},
year = {2013},
date = {2013-01-01},
journal = {Pedosphere},
volume = {23},
number = {2},
pages = {143-159},
abstract = {Soil contamination by metals from anthropogenic activities (e.g., mining and smelting) is a major concern for the environment and human health. environmental availability of cadmium (cd), lead (pb), zinc (zn), copper (cu), and indium (in) in 27 urban soils located around two former pb and zn smelters in northern france were studied by analysing the chemical forms of these metals and evaluating their phytoavailability. these metals were determined using flame or electrothermal absorption atomic spectrometry (faas or etaas), depending on their concentration levels. after optimisation of the etaas method, characteristic mass of in in water and aqua regia were 9.9 and 18 pg, respectively, showing the high sensitivity of the analytical procedure. metal partitioning was conducted using a four-step sequential extraction procedure. the results showed that cd and zn were mainly in the acid-extractable and reducible forms in the urban soils studied. in contrast, pb and in were largely in the reducible fraction. however, in some samples, the amount of in extracted in the residual or exchangeable fraction was higher than that in the reducible fraction. copper was mainly found in the reducible and residual fractions. a pot experiment was conducted in a glasshouse with seven soils (six contaminated and one uncontaminated) and two plant species, ryegrass and lettuce. the results showed transfer of metals from the contaminated soils to the shoots of ryegrass and the edible part of lettuce. the metal bioconcentration factor was in the order of cd >> cu > in > zn >> pb for lettuce leaves, whereas for ryegrass shoots, three orders were found, cd > zn > cu >> in > pb, cd >= in > zn > cu >> pb, and zn > cd > cu > in > pb, depending on the physico-chemical properties of the soils, such as ph, cation exchange capacity, carbonates, and organic matter. it was established that the metal toxicity was related to the contamination levels and the physico-chemical properties, including ph, organic matter, and in a lesser extent, ca, mg, and phosphorus contents, of the soils. however, it was shown that lettuce could grow on soils having high cd and caco3 contents. cadmium was one of the most available metals while pb was always the least available in the soils studied.},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
Soil contamination by metals from anthropogenic activities (e.g., mining and smelting) is a major concern for the environment and human health. environmental availability of cadmium (cd), lead (pb), zinc (zn), copper (cu), and indium (in) in 27 urban soils located around two former pb and zn smelters in northern france were studied by analysing the chemical forms of these metals and evaluating their phytoavailability. these metals were determined using flame or electrothermal absorption atomic spectrometry (faas or etaas), depending on their concentration levels. after optimisation of the etaas method, characteristic mass of in in water and aqua regia were 9.9 and 18 pg, respectively, showing the high sensitivity of the analytical procedure. metal partitioning was conducted using a four-step sequential extraction procedure. the results showed that cd and zn were mainly in the acid-extractable and reducible forms in the urban soils studied. in contrast, pb and in were largely in the reducible fraction. however, in some samples, the amount of in extracted in the residual or exchangeable fraction was higher than that in the reducible fraction. copper was mainly found in the reducible and residual fractions. a pot experiment was conducted in a glasshouse with seven soils (six contaminated and one uncontaminated) and two plant species, ryegrass and lettuce. the results showed transfer of metals from the contaminated soils to the shoots of ryegrass and the edible part of lettuce. the metal bioconcentration factor was in the order of cd >> cu > in > zn >> pb for lettuce leaves, whereas for ryegrass shoots, three orders were found, cd > zn > cu >> in > pb, cd >= in > zn > cu >> pb, and zn > cd > cu > in > pb, depending on the physico-chemical properties of the soils, such as ph, cation exchange capacity, carbonates, and organic matter. it was established that the metal toxicity was related to the contamination levels and the physico-chemical properties, including ph, organic matter, and in a lesser extent, ca, mg, and phosphorus contents, of the soils. however, it was shown that lettuce could grow on soils having high cd and caco3 contents. cadmium was one of the most available metals while pb was always the least available in the soils studied. |
2012Conference ER4 Auteurs : Pelfrêne, Aurélie; Waterlot, Christophe; Mazzuca, Muriel; Nisse, Catherine; Bidar, Géraldine; Douay, Francis Modélisation de la bioaccessibilité orale de Cd et Pb au regard des paramètres physico-chimiques de sols agricoles fortement contaminés : Application à un site contaminé du Nord-Pas de Calais Intersol. 27-30 mars 2012, Paris, 2012, (ACTN). @conference{Pelfrene2012c,
title = {Modélisation de la bioaccessibilité orale de Cd et Pb au regard des paramètres physico-chimiques de sols agricoles fortement contaminés : Application à un site contaminé du Nord-Pas de Calais},
author = {Aurélie Pelfrêne and Christophe Waterlot and Muriel Mazzuca and Catherine Nisse and Géraldine Bidar and Francis Douay},
year = {2012},
date = {2012-01-01},
booktitle = {Intersol. 27-30 mars 2012, Paris},
note = {ACTN},
keywords = {ER4},
pubstate = {published},
tppubtype = {conference}
}
|
2012Journal Article ER4 Auteurs : Pelfrêne, Aurélie; Waterlot, Christophe; Mazzuca, Muriel; Nisse, Catherine; Cuny, Damien; Richard, Antoine; Denys, Sébastien; Heyman, Christophe; Roussel, Hélène; Bidar, Géraldine; Douay, Francis Bioaccessibility of trace elements as affected by soil parameters in smelter-contaminated agricultural soils: A statistical modeling approach In: Environmental Pollution, vol. 160, pp. 130-138, 2012, (ACL). Abstract @article{Pelfrene2012a,
title = {Bioaccessibility of trace elements as affected by soil parameters in smelter-contaminated agricultural soils: A statistical modeling approach},
author = {Aurélie Pelfrêne and Christophe Waterlot and Muriel Mazzuca and Catherine Nisse and Damien Cuny and Antoine Richard and Sébastien Denys and Christophe Heyman and Hélène Roussel and Géraldine Bidar and Francis Douay},
year = {2012},
date = {2012-01-01},
journal = {Environmental Pollution},
volume = {160},
pages = {130-138},
abstract = {An investigation was undertaken to identify the most significant soil parameters that can be used to predict cd, pb, and zn bioaccessibility in smelter-contaminated agricultural soils. a robust model was established from an extended database of soils by using: (i) a training set of 280 samples to select the main soil parameters, to define the best population to be taken into account for the model elaboration, and to construct multivariate regression models, and (ii) a test set of 110 samples to validate the ability of the regression models. total carbonate, organic matter, sand, p2o5, free feemn oxide, and pseudototal al and trace element (te) contents appeared as the main variables governing te bioaccessibility. the statistical modeling approach was reasonably successful, indicating that the main soil factors influencing the bioaccessibility of tes were taken into account and the predictions could be applicable for further risk evaluation in the studied area.},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
An investigation was undertaken to identify the most significant soil parameters that can be used to predict cd, pb, and zn bioaccessibility in smelter-contaminated agricultural soils. a robust model was established from an extended database of soils by using: (i) a training set of 280 samples to select the main soil parameters, to define the best population to be taken into account for the model elaboration, and to construct multivariate regression models, and (ii) a test set of 110 samples to validate the ability of the regression models. total carbonate, organic matter, sand, p2o5, free feemn oxide, and pseudototal al and trace element (te) contents appeared as the main variables governing te bioaccessibility. the statistical modeling approach was reasonably successful, indicating that the main soil factors influencing the bioaccessibility of tes were taken into account and the predictions could be applicable for further risk evaluation in the studied area. |
2012Journal Article ER4 Auteurs : Waterlot, Christophe; Bidar, Géraldine; Pruvot, Christelle; Douay, Francis Effects of grinding and shaking on Cd, Pb and Zn distribution in anthropogenically impacted soils In: Talanta, vol. 98, pp. 185-196, 2012, (ACL). Abstract @article{Waterlot2012,
title = {Effects of grinding and shaking on Cd, Pb and Zn distribution in anthropogenically impacted soils},
author = {Christophe Waterlot and Géraldine Bidar and Christelle Pruvot and Francis Douay},
year = {2012},
date = {2012-01-01},
journal = {Talanta},
volume = {98},
pages = {185-196},
abstract = {The effectsofgrinding size andshaking process on the results ofcd (cadmium), pb (lead) and zn (zinc) distribution measurements three agricultural and three kitchen garden soils highly contaminated by past atmospheric fallout of two lead and zinc smelters in northern france were studied. the physico-chemical parameters and pseudo-total concentration of metals within these soils were determined. the fractionation of metals was performed in triplicate, using the procedure recommended by the standards, measurements and testing program (sm&t), on each air-dried soil sample, ground to pass through 2-mm, 0.315-mm and 0.250-mm sieves and using a reciprocating or rotary shaker. the samples were analysed by flame or electrothermal absorption atomic spectrometry using a self-reversal background system. for both shaking processes, the grinding size had no effecton the fractionation of metals in contaminated agricultural soils. in contrast, using a reciprocating shaker, the fractionation of metals in the kitchen garden samples sieved at <2 mm was so different that in the samples prepared to pass through the 0.315-mm and 0.250-mm sieves. therefore changes (use of a 50 ml graduated polypropylene centrifuge tube, evaporation of the solution to a fixed volume in step 3 and the use of an automatic shaking heating bath) were made to the initial procedure and a rotary shaker was used to improve the suspension of the soil samples during extraction. for all grinding sizes, the fractionation of the three metals contained in the contaminated kitchen garden soil samples was successfully achieved. nevertheless, some discrepancies from samples sieved at <2 mm were obtained. on the other hand, it is worth noting that the effectof the type of shaker on the distribution of metal depended on the soil and the grinding size. from an analytical point of view, precision and trueness were improved after optimisation of the procedure for all sequential extraction procedure steps. the best results were obtained for samples sieved at <0.250 mm. similar trends were obtained using the crm bcr®-701 certified material. all the results showed that optimisation of the sequential extraction procedure could be adopted for the cd-, pb- and zn-partitioning in contaminated kitchen garden soils with high-level anthropogenic sources.},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
The effectsofgrinding size andshaking process on the results ofcd (cadmium), pb (lead) and zn (zinc) distribution measurements three agricultural and three kitchen garden soils highly contaminated by past atmospheric fallout of two lead and zinc smelters in northern france were studied. the physico-chemical parameters and pseudo-total concentration of metals within these soils were determined. the fractionation of metals was performed in triplicate, using the procedure recommended by the standards, measurements and testing program (sm&t), on each air-dried soil sample, ground to pass through 2-mm, 0.315-mm and 0.250-mm sieves and using a reciprocating or rotary shaker. the samples were analysed by flame or electrothermal absorption atomic spectrometry using a self-reversal background system. for both shaking processes, the grinding size had no effecton the fractionation of metals in contaminated agricultural soils. in contrast, using a reciprocating shaker, the fractionation of metals in the kitchen garden samples sieved at <2 mm was so different that in the samples prepared to pass through the 0.315-mm and 0.250-mm sieves. therefore changes (use of a 50 ml graduated polypropylene centrifuge tube, evaporation of the solution to a fixed volume in step 3 and the use of an automatic shaking heating bath) were made to the initial procedure and a rotary shaker was used to improve the suspension of the soil samples during extraction. for all grinding sizes, the fractionation of the three metals contained in the contaminated kitchen garden soil samples was successfully achieved. nevertheless, some discrepancies from samples sieved at <2 mm were obtained. on the other hand, it is worth noting that the effectof the type of shaker on the distribution of metal depended on the soil and the grinding size. from an analytical point of view, precision and trueness were improved after optimisation of the procedure for all sequential extraction procedure steps. the best results were obtained for samples sieved at <0.250 mm. similar trends were obtained using the crm bcr®-701 certified material. all the results showed that optimisation of the sequential extraction procedure could be adopted for the cd-, pb- and zn-partitioning in contaminated kitchen garden soils with high-level anthropogenic sources. |
2011Conference ER4 Auteurs : Douay, Francis; Lopareva-Pohu, Alena; Pourrut, Bertrand; Waterlot, Christophe; Garçon, Guillaume; Bidar, Géraldine; Pruvot, Christelle; Shirali, Pirouz Impacts d’un mode de phytomanagement sur des sols fortement contaminés par des métaux ValBiom, 8èmes rencontres de la Biomasse. 26 octobre 2011, Gembloux (Belgique), 2011, (COM). @conference{Douay2011b,
title = {Impacts d’un mode de phytomanagement sur des sols fortement contaminés par des métaux},
author = {Francis Douay and Alena Lopareva-Pohu and Bertrand Pourrut and Christophe Waterlot and Guillaume Garçon and Géraldine Bidar and Christelle Pruvot and Pirouz Shirali},
year = {2011},
date = {2011-01-01},
booktitle = {ValBiom, 8èmes rencontres de la Biomasse. 26 octobre 2011, Gembloux (Belgique)},
note = {COM},
keywords = {ER4},
pubstate = {published},
tppubtype = {conference}
}
|
2011Conference ER4 Auteurs : Douay, Francis; Pourrut, Bertrand; Waterlot, Christophe; Lopareva-Pohu, Alena; Pruvot, Christelle; Garçon, Guillaume; Bidar, Géraldine; Shirali, Pirouz Fly ash-aided phytostabilisation of highly contaminated soils: assessment of field trial after 8 years 11th International Conference on the Biogeochemistry of Trace Elements (ICOBTE). 3-7 July 2011, Florence (Italie), 2011, (ACTI). @conference{Douay2011c,
title = {Fly ash-aided phytostabilisation of highly contaminated soils: assessment of field trial after 8 years},
author = {Francis Douay and Bertrand Pourrut and Christophe Waterlot and Alena Lopareva-Pohu and Christelle Pruvot and Guillaume Garçon and Géraldine Bidar and Pirouz Shirali},
year = {2011},
date = {2011-01-01},
booktitle = {11th International Conference on the Biogeochemistry of Trace Elements (ICOBTE). 3-7 July 2011, Florence (Italie)},
note = {ACTI},
keywords = {ER4},
pubstate = {published},
tppubtype = {conference}
}
|
2011Journal Article ER4 Auteurs : Lopareva-Pohu, Alena; Pourrut, Bertrand; Waterlot, Christophe; Garçon, Guillaume; Bidar, Géraldine; Pruvot, Christelle; Shirali, Pirouz; Douay, Francis Assessment of fly ash-aided phytostabilisation of highly contaminated soils after an 8-year field trial Part 1. Influence on soil parameters and metal extractability In: Science of the Total Environment, vol. 409, no. 3, pp. 647-654, 2011, (ACL). Abstract @article{Lopareva-Pohu2011b,
title = {Assessment of fly ash-aided phytostabilisation of highly contaminated soils after an 8-year field trial Part 1. Influence on soil parameters and metal extractability},
author = {Alena Lopareva-Pohu and Bertrand Pourrut and Christophe Waterlot and Guillaume Garçon and Géraldine Bidar and Christelle Pruvot and Pirouz Shirali and Francis Douay},
year = {2011},
date = {2011-01-01},
journal = {Science of the Total Environment},
volume = {409},
number = {3},
pages = {647-654},
abstract = {Sustainable management of large surface areas contaminated with trace elements is a real challenge, since currently applied remediation techniques are too expensive for these areas. aided phytostabilisation appears to be a cost efficient technique to reduce metal mobility in contaminated soils and contaminated particle spread. in this context, this study aimed at evaluating the long-term efficiency of aided phytostabilisation on former agricultural soils highly contaminated with trace elements. the influence of afforestation and fly ash amendments to reduce metal mobility was investigated. before being planted with a tree mix, the study site was divided into three plots: a reference plot with no amendment, the second amended with silico-aluminous fly ash and the third with sulfo-calcic fly ash. after eight years, some soil physico-chemical parameters, including cadmium (cd), lead (pb) and zinc (zn) extractability were modified. in particular, ph decreased on the whole site while organic carbon content increased. the alteration of these parameters influencing trace element mobility is explained by afforestation. over time, concentrations of cacl2-extractable metals increased and were correlated with the soil ph decrease. in the amended soils, extractable cd, pb and zn concentrations were lower than in the reference soil. the results indicated that the two fly ashes buffered natural soil acidification due to vegetation development and limited trace element mobility and thus could limit their bioavailability. for long-term phytostabilisation, special attention should be focused on the soil ph, metal mobility and phytoavailability analysis. (c) 2010 elsevier b.v. all rights reserved.},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
Sustainable management of large surface areas contaminated with trace elements is a real challenge, since currently applied remediation techniques are too expensive for these areas. aided phytostabilisation appears to be a cost efficient technique to reduce metal mobility in contaminated soils and contaminated particle spread. in this context, this study aimed at evaluating the long-term efficiency of aided phytostabilisation on former agricultural soils highly contaminated with trace elements. the influence of afforestation and fly ash amendments to reduce metal mobility was investigated. before being planted with a tree mix, the study site was divided into three plots: a reference plot with no amendment, the second amended with silico-aluminous fly ash and the third with sulfo-calcic fly ash. after eight years, some soil physico-chemical parameters, including cadmium (cd), lead (pb) and zinc (zn) extractability were modified. in particular, ph decreased on the whole site while organic carbon content increased. the alteration of these parameters influencing trace element mobility is explained by afforestation. over time, concentrations of cacl2-extractable metals increased and were correlated with the soil ph decrease. in the amended soils, extractable cd, pb and zn concentrations were lower than in the reference soil. the results indicated that the two fly ashes buffered natural soil acidification due to vegetation development and limited trace element mobility and thus could limit their bioavailability. for long-term phytostabilisation, special attention should be focused on the soil ph, metal mobility and phytoavailability analysis. (c) 2010 elsevier b.v. all rights reserved. |
2011Journal Article ER4 Auteurs : Lopareva-Pohu, Alena; Verdin, Anthony; Garçon, Guillaume; Lounès-Hadj-Sahraoui, Anissa; Pourrut, Bertrand; Debiane, Djouher; Waterlot, Christophe; Laruelle, Frédéric; Bidar, Géraldine; Douay, Francis; Shirali, Pirouz Influence of fly ash aided phytostabilisation of Pb, Cd and Zn highly contaminated soils on Lolium perenne and Trifolium repens metal transfer and physiological stress In: Environmental Pollution, vol. 159, no. 6, pp. 1721-1729, 2011, (ACL). Abstract @article{Lopareva-Pohu2011a,
title = {Influence of fly ash aided phytostabilisation of Pb, Cd and Zn highly contaminated soils on Lolium perenne and Trifolium repens metal transfer and physiological stress},
author = {Alena Lopareva-Pohu and Anthony Verdin and Guillaume Garçon and Anissa Lounès-Hadj-Sahraoui and Bertrand Pourrut and Djouher Debiane and Christophe Waterlot and Frédéric Laruelle and Géraldine Bidar and Francis Douay and Pirouz Shirali},
year = {2011},
date = {2011-01-01},
journal = {Environmental Pollution},
volume = {159},
number = {6},
pages = {1721-1729},
abstract = {Due to anthropogenic activities, large extends of soils are highly contaminated by metal trace element (mte). aided phytostabilisation aims to establish a vegetation cover in order to promote in situ immobilisation of trace elements by combining the use of metal-tolerant plants and inexpensive mineral or organic soil amendments. eight years after coal fly ash (cfa) soil amendment, mte bioavailability and uptake by two plants, lolium perenne and trifolium repens, were evaluated, as some biological markers reflecting physiological stress. results showed that the two plant species under study were suitable to reduce the mobility and the availability of these elements. moreover, the plant growth was better on cfa amended mte-contaminated soils, and the plant sensitivity to mte-induced physiological stress, as studied through photosynthetic pigment contents and oxidative damage was lower or similar. in conclusion, these results supported the usefulness of aided phytostabilisation of mte-highly contaminated soils. highlights ► aided phytostabilisation aims to establish a vegetation cover in order to promote immobilisation of mte. ► 8 years after the soil amendments, a pot culture study was carried out in greenhouse conditions. ► mte bioavailability and uptake by the two plants was drastically decreased with amendments. ► our results support the usefulness of aided phytostabilisation of mte-highly contaminated soils. ► cfa addition contributed to the reduction of the mte mobility and availability for the plants},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
Due to anthropogenic activities, large extends of soils are highly contaminated by metal trace element (mte). aided phytostabilisation aims to establish a vegetation cover in order to promote in situ immobilisation of trace elements by combining the use of metal-tolerant plants and inexpensive mineral or organic soil amendments. eight years after coal fly ash (cfa) soil amendment, mte bioavailability and uptake by two plants, lolium perenne and trifolium repens, were evaluated, as some biological markers reflecting physiological stress. results showed that the two plant species under study were suitable to reduce the mobility and the availability of these elements. moreover, the plant growth was better on cfa amended mte-contaminated soils, and the plant sensitivity to mte-induced physiological stress, as studied through photosynthetic pigment contents and oxidative damage was lower or similar. in conclusion, these results supported the usefulness of aided phytostabilisation of mte-highly contaminated soils. highlights ► aided phytostabilisation aims to establish a vegetation cover in order to promote immobilisation of mte. ► 8 years after the soil amendments, a pot culture study was carried out in greenhouse conditions. ► mte bioavailability and uptake by the two plants was drastically decreased with amendments. ► our results support the usefulness of aided phytostabilisation of mte-highly contaminated soils. ► cfa addition contributed to the reduction of the mte mobility and availability for the plants |
2011Journal Article ER4 Auteurs : Pelfrêne, Aurélie; Waterlot, Christophe; Mazzuca, Muriel; Nisse, Catherine; Bidar, Géraldine; Douay, Francis Assessing Cd, Pb, Zn mobility and human bioaccessibility in smelter-contaminated agricultural topsoils (northern France) In: Environmental Geochemistry and Health, vol. 33, no. 5, pp. 477-493, 2011, (ACL). Abstract @article{Pelfrene2011b,
title = {Assessing Cd, Pb, Zn mobility and human bioaccessibility in smelter-contaminated agricultural topsoils (northern France)},
author = {Aurélie Pelfrêne and Christophe Waterlot and Muriel Mazzuca and Catherine Nisse and Géraldine Bidar and Francis Douay},
year = {2011},
date = {2011-01-01},
journal = {Environmental Geochemistry and Health},
volume = {33},
number = {5},
pages = {477-493},
abstract = {The extractability of cd, pb, and zn was investigated in contaminated agricultural topsoils located in an area highly affected by the past atmospheric emissions of two smelters in northern france in order to assess their mobility and human bioaccessibility. the determination of cd, pb, and zn bioaccessibility (unified barge method, in vitro test) was made to evaluate the absolute trace element (te) bioavailability. the results highlighted differences in bioaccessibility between cd, pb, and zn (cd[pb[ zn). the mean values of the bioaccessible fractions of cd, pb, and zn during the gastric phase were 82, 55, and 33%, respectively, of the pseudototal concentrations, whereas during the gastrointestinal phase, the bioaccessible fractions of metals decreased to 45, 20, and 10%, respectively. stepwise multiple regression analysis showed that human bioaccessibility was affected by various physicochemical parameters (i.e., sand, carbonates, organic matter, assimilated p, free al oxides, and pseudototal fe contents). sequential extractions were performed as an indication of the te availability in these soils. cadmium occurred in the more available fractions, pb was mostly present as bound by oxides, and a significant contribution to the pseudototal zn concentration was defined as the unavailable residual form related to the crystalline structures of minerals. the concepts of bioavailability and bioaccessibility are important for quantifying the risks associated with exposure to environmental pollutants and providing more realistic information for human health},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
The extractability of cd, pb, and zn was investigated in contaminated agricultural topsoils located in an area highly affected by the past atmospheric emissions of two smelters in northern france in order to assess their mobility and human bioaccessibility. the determination of cd, pb, and zn bioaccessibility (unified barge method, in vitro test) was made to evaluate the absolute trace element (te) bioavailability. the results highlighted differences in bioaccessibility between cd, pb, and zn (cd[pb[ zn). the mean values of the bioaccessible fractions of cd, pb, and zn during the gastric phase were 82, 55, and 33%, respectively, of the pseudototal concentrations, whereas during the gastrointestinal phase, the bioaccessible fractions of metals decreased to 45, 20, and 10%, respectively. stepwise multiple regression analysis showed that human bioaccessibility was affected by various physicochemical parameters (i.e., sand, carbonates, organic matter, assimilated p, free al oxides, and pseudototal fe contents). sequential extractions were performed as an indication of the te availability in these soils. cadmium occurred in the more available fractions, pb was mostly present as bound by oxides, and a significant contribution to the pseudototal zn concentration was defined as the unavailable residual form related to the crystalline structures of minerals. the concepts of bioavailability and bioaccessibility are important for quantifying the risks associated with exposure to environmental pollutants and providing more realistic information for human health |
2011Journal Article ER4 Auteurs : Pourrut, Bertrand; Lopareva-Pohu, Alena; Pruvot, Christelle; Garçon, Guillaume; Verdin, Anthony; Waterlot, Christophe; Bidar, Géraldine; Shirali, Pirouz; Douay, Francis Assessment of fly ash-aided phytostabilisation of highly contaminated soils after an 8-year field trial. Part 2. Influence on plants In: Science of the Total Environment, vol. 409, pp. 4504-4510, 2011, (ACL). Abstract @article{Pourrut2011a,
title = {Assessment of fly ash-aided phytostabilisation of highly contaminated soils after an 8-year field trial. Part 2. Influence on plants},
author = {Bertrand Pourrut and Alena Lopareva-Pohu and Christelle Pruvot and Guillaume Garçon and Anthony Verdin and Christophe Waterlot and Géraldine Bidar and Pirouz Shirali and Francis Douay},
year = {2011},
date = {2011-01-01},
journal = {Science of the Total Environment},
volume = {409},
pages = {4504-4510},
abstract = {Aided phytostabilisation is a cost-efficient technique to manage metal-contaminated areas, particularly in the presence of extensive pollution. plant establishment and survival in highly metal-contaminated soils are crucial for phytostabilisation success, as metal toxicity for plants is widely reported. a relevant phytostabilisation solution must limit metal transfer through the food chain. therefore, this study aimed at evaluating the long-term efficiency of aided phytostabilisation on former agricultural soils highly contaminated by cadmium, lead, and zinc. the influence of afforestation and fly ash amendments on reducing metal phytoavailability was investigated as were their effects on plant development. before being planted with a tree mix, the site was divided into three plots: a reference plot with no amendment, a plot amended with silico-aluminous fly ash and one with sulfo-calcic fly ash. unlike salix alba and quercus robur, alnus glutinosa, acer pseudoplatanus and robinia pseudoacacia grew well on the site and accumulated, overall, quite low concentrations of metals in their leaves and young twigs. this suggests that these three species have an excluder phenotype for cd, zn and pb. after 8 years, metal availability to a. glutinosa, a. pseudoplatanus and r. pseudoacacia, and translocation to their above-ground parts, strongly decreased in fly ash-amended soils. such decreases fit well together with the depletion of cacl2-extractable metals in amended soils. although both fly ashes were effective to decrease cd, pb and zn concentrations in above-ground parts of trees, the sulfo-calcic ash was more efficient.},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
Aided phytostabilisation is a cost-efficient technique to manage metal-contaminated areas, particularly in the presence of extensive pollution. plant establishment and survival in highly metal-contaminated soils are crucial for phytostabilisation success, as metal toxicity for plants is widely reported. a relevant phytostabilisation solution must limit metal transfer through the food chain. therefore, this study aimed at evaluating the long-term efficiency of aided phytostabilisation on former agricultural soils highly contaminated by cadmium, lead, and zinc. the influence of afforestation and fly ash amendments on reducing metal phytoavailability was investigated as were their effects on plant development. before being planted with a tree mix, the site was divided into three plots: a reference plot with no amendment, a plot amended with silico-aluminous fly ash and one with sulfo-calcic fly ash. unlike salix alba and quercus robur, alnus glutinosa, acer pseudoplatanus and robinia pseudoacacia grew well on the site and accumulated, overall, quite low concentrations of metals in their leaves and young twigs. this suggests that these three species have an excluder phenotype for cd, zn and pb. after 8 years, metal availability to a. glutinosa, a. pseudoplatanus and r. pseudoacacia, and translocation to their above-ground parts, strongly decreased in fly ash-amended soils. such decreases fit well together with the depletion of cacl2-extractable metals in amended soils. although both fly ashes were effective to decrease cd, pb and zn concentrations in above-ground parts of trees, the sulfo-calcic ash was more efficient. |
2011Journal Article ER4 Auteurs : Waterlot, Christophe; Bidar, Géraldine; Pruvot, Christelle; Douay, Francis Analysis of cadmium in water extracts from contaminated soils with high arsenic and iron concentration levels In: Journal of Environmental Science and Engineering, vol. 5, pp. 271-280, 2011, (ACL). Abstract @article{Waterlot2011,
title = {Analysis of cadmium in water extracts from contaminated soils with high arsenic and iron concentration levels},
author = {Christophe Waterlot and Géraldine Bidar and Christelle Pruvot and Francis Douay},
year = {2011},
date = {2011-01-01},
journal = {Journal of Environmental Science and Engineering},
volume = {5},
pages = {271-280},
abstract = {Cadmium (cd) concentrations in the water extracts often contaminated soils by arsenic (as) with various iron (fe) contents were measured using inductively coupled plasma atomic emission spectrometry (icp-aes) and electrothermal atomic absorption spectrometry (etaas). due to the potential spectral interferences of as and fe in the quantification of cd, two methods were used for the background compensation. the first method was based on the use of a deuterium lamp (bgcd2 mode). the second one required a cd hollow cathode lamp pulsated with a current for which the intensity varies in the course of time (bgcsr mode). the results showed that the choices of the analytical technique and the method used for the background compensation depend on the cd, as and fe concentrations in the solution and the concentration ratios as/cd or/and fe/cd. in comparison with the icp-aes and the etaas in combination with the bgcd2 mode, it was shown that the high-speed self-reversal method (hssr) was a more appropriate method to correct as and fe spectral interferences during the cd measurements. on the other hand, depending on the cd concentration, it was established that no significant fe interference occurred during the cd determination even if fe concentration was 50 mg/l, reflecting the efficiency of the hssr method to overcome the fe interferences in the determination of cd concentration by etaas without any matrix modifier in water extracts},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
Cadmium (cd) concentrations in the water extracts often contaminated soils by arsenic (as) with various iron (fe) contents were measured using inductively coupled plasma atomic emission spectrometry (icp-aes) and electrothermal atomic absorption spectrometry (etaas). due to the potential spectral interferences of as and fe in the quantification of cd, two methods were used for the background compensation. the first method was based on the use of a deuterium lamp (bgcd2 mode). the second one required a cd hollow cathode lamp pulsated with a current for which the intensity varies in the course of time (bgcsr mode). the results showed that the choices of the analytical technique and the method used for the background compensation depend on the cd, as and fe concentrations in the solution and the concentration ratios as/cd or/and fe/cd. in comparison with the icp-aes and the etaas in combination with the bgcd2 mode, it was shown that the high-speed self-reversal method (hssr) was a more appropriate method to correct as and fe spectral interferences during the cd measurements. on the other hand, depending on the cd concentration, it was established that no significant fe interference occurred during the cd determination even if fe concentration was 50 mg/l, reflecting the efficiency of the hssr method to overcome the fe interferences in the determination of cd concentration by etaas without any matrix modifier in water extracts |
2010Journal Article ER4 Auteurs : Pohu-Lopareva, Alena; Roussel, Hélène; Waterlot, Christophe; Garçon, Guillaume; Bidar, Géraldine; Pruvot, Christelle; Baize, Denis; Shirali, A; Douay, Francis Asymétrie fluctuante des feuilles d’Alnus glutinosa: Indicateur de stress dans le cadre d’une phytostabilisation aidée sur des sols fortement pollués par des éléments traces métalliques In: Bulletin Bodenkundliche Gesellschaft der Schweiz, vol. 30, pp. 51-56, 2010. @article{Pohu-Lopareva2010,
title = {Asymétrie fluctuante des feuilles d’Alnus glutinosa: Indicateur de stress dans le cadre d’une phytostabilisation aidée sur des sols fortement pollués par des éléments traces métalliques},
author = {Alena Pohu-Lopareva and Hélène Roussel and Christophe Waterlot and Guillaume Garçon and Géraldine Bidar and Christelle Pruvot and Denis Baize and A Shirali and Francis Douay},
year = {2010},
date = {2010-01-01},
journal = {Bulletin Bodenkundliche Gesellschaft der Schweiz},
volume = {30},
pages = {51-56},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
|
2009Journal Article ER4 Auteurs : Bidar, Géraldine; Garçon, Guillaume; Pruvot, Christelle; Verdin, Anthony; Shirali, Pirouz; Douay, Francis Seasonal and annual variations of the metal uptake and toxicity in Trifolium repens and Lolium perenne growing in a heavy metal contaminated field In: Environmental Science and Pollution Research, vol. 16, no. 1, pp. 42-53, 2009, (ACL). Abstract @article{Bidar2009,
title = {Seasonal and annual variations of the metal uptake and toxicity in Trifolium repens and Lolium perenne growing in a heavy metal contaminated field},
author = {Géraldine Bidar and Guillaume Garçon and Christelle Pruvot and Anthony Verdin and Pirouz Shirali and Francis Douay},
year = {2009},
date = {2009-01-01},
journal = {Environmental Science and Pollution Research},
volume = {16},
number = {1},
pages = {42-53},
abstract = {Background, aim, and scope the reclamation of nonferrous metal-polluted soil by phytoremediation requires an overall and permanent plant cover. to select the most suitable plant species, it is necessary to study metal effects on plants over the time, thereby checking that metals remain stored in root systems and not transferred to aerial parts. in this purpose, the seasonal and annual variations of metal bioaccumulation, transfer, and phytotoxicity in trifolium repens and lolium perenne grown in a cd-, pb-, and zn-contaminated soil were also studied. materials and methods the experimental site was located near a closed smelter. in spring 2004, two areas were sown with t. repens and l. perenne, respectively. thereafter, the samplings of plant roots and shoots and surrounding soils were realized in autumn 2004 and spring and autumn 2005. the soil agronomic characteristics, the cd, pb, and zn concentrations in the surrounded soils and plant organs, as well as the oxidative alterations (superoxide dismutase [sod], malondialdehyde [mda], and 8-hydroxy-2′-deoxyguanosine [8-ohdg]) in plant organs were carried out. results whatever the sampling period, metal concentrations in soils and plants were higher than background values. contrary to the soils, the fluctuations of metal concentrations were observed in plant organs over the time. bioaccumulation and transfer factors confirmed that metals were preferentially accumulated in the roots as follows: cd>zn>pb, and their transfer to shoots was limited. foliar metal deposition was also observed. the results showed that there were seasonal and annual variations of metal accumulation in the two studied plant species. these variations differed according to the organs and followed nearly the same pattern for the two species. oxidative alterations were observed in plant organs with regard to sod antioxidant activities, mda, and 8-ohdg concentrations. these alterations vary according to the temporal variations of metal concentrations. discussion metal concentrations in surrounded soils and plant organs showed the effective contamination by industrial dust emissions. metals absorbed by plants were mainly stored in the roots. with regard to this storage, the plants seemed to limit the metal transfer to their aerial parts over the time, thereby indicating their availability for metal phytostabilization. aerial deposition was another source of plant exposure to nonferrous metals. despite the occurrence ofmetal-induced oxidative alterations in plant organs, both plant species seemed to tolerate a high metal concentration in soils. conclusions taken together, these results indicated that t. repens and l. perenne were able to form a plant cover on highly cd-, pb-, and zn-polluted soils, to limit the metal transfer to their aerial parts and were relatively metal-tolerant. all these characteristics made them suitable for phytostabilization on metal-contaminated soils. these findings also highlighted the necessity to take into account seasonal and annual variations for a future phytomanagement. recommendations and perspectives in this work, the behavior of plant species grown in metal-polluted soil has been studied during 2 years. obviously, this time is too short to ensure that metals remain accumulated in the root system and few are transferred in aerial parts over the time. it is why regular monitoring should be achieved during more than a decade after the settlement of the plant cover. this work will be completed by the study of the t. repens and l. perenne effects on mobility of metals in order to evaluate the quantities of pollutants which could be absorbed by the biota and transferred to groundwater. bioaccessibility tests could be also realized on polluted soils in order to evaluate the phytostabilization impacts on the exposition risks for humans. keywords bioaccumulation factors . l. perenne . nonferrous metal-contaminated soil . oxidative stress . phytostabilization . seasonal and annual variations . t. repens . transfer factors},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
Background, aim, and scope the reclamation of nonferrous metal-polluted soil by phytoremediation requires an overall and permanent plant cover. to select the most suitable plant species, it is necessary to study metal effects on plants over the time, thereby checking that metals remain stored in root systems and not transferred to aerial parts. in this purpose, the seasonal and annual variations of metal bioaccumulation, transfer, and phytotoxicity in trifolium repens and lolium perenne grown in a cd-, pb-, and zn-contaminated soil were also studied. materials and methods the experimental site was located near a closed smelter. in spring 2004, two areas were sown with t. repens and l. perenne, respectively. thereafter, the samplings of plant roots and shoots and surrounding soils were realized in autumn 2004 and spring and autumn 2005. the soil agronomic characteristics, the cd, pb, and zn concentrations in the surrounded soils and plant organs, as well as the oxidative alterations (superoxide dismutase [sod], malondialdehyde [mda], and 8-hydroxy-2′-deoxyguanosine [8-ohdg]) in plant organs were carried out. results whatever the sampling period, metal concentrations in soils and plants were higher than background values. contrary to the soils, the fluctuations of metal concentrations were observed in plant organs over the time. bioaccumulation and transfer factors confirmed that metals were preferentially accumulated in the roots as follows: cd>zn>pb, and their transfer to shoots was limited. foliar metal deposition was also observed. the results showed that there were seasonal and annual variations of metal accumulation in the two studied plant species. these variations differed according to the organs and followed nearly the same pattern for the two species. oxidative alterations were observed in plant organs with regard to sod antioxidant activities, mda, and 8-ohdg concentrations. these alterations vary according to the temporal variations of metal concentrations. discussion metal concentrations in surrounded soils and plant organs showed the effective contamination by industrial dust emissions. metals absorbed by plants were mainly stored in the roots. with regard to this storage, the plants seemed to limit the metal transfer to their aerial parts over the time, thereby indicating their availability for metal phytostabilization. aerial deposition was another source of plant exposure to nonferrous metals. despite the occurrence ofmetal-induced oxidative alterations in plant organs, both plant species seemed to tolerate a high metal concentration in soils. conclusions taken together, these results indicated that t. repens and l. perenne were able to form a plant cover on highly cd-, pb-, and zn-polluted soils, to limit the metal transfer to their aerial parts and were relatively metal-tolerant. all these characteristics made them suitable for phytostabilization on metal-contaminated soils. these findings also highlighted the necessity to take into account seasonal and annual variations for a future phytomanagement. recommendations and perspectives in this work, the behavior of plant species grown in metal-polluted soil has been studied during 2 years. obviously, this time is too short to ensure that metals remain accumulated in the root system and few are transferred in aerial parts over the time. it is why regular monitoring should be achieved during more than a decade after the settlement of the plant cover. this work will be completed by the study of the t. repens and l. perenne effects on mobility of metals in order to evaluate the quantities of pollutants which could be absorbed by the biota and transferred to groundwater. bioaccessibility tests could be also realized on polluted soils in order to evaluate the phytostabilization impacts on the exposition risks for humans. keywords bioaccumulation factors . l. perenne . nonferrous metal-contaminated soil . oxidative stress . phytostabilization . seasonal and annual variations . t. repens . transfer factors |
2009Journal Article ER4 Auteurs : Douay, Francis; Pruvot, Christelle; Waterlot, Christophe; Fritsch, Clémentine; Fourrier, Hervé; Loriette, Alexandre; Bidar, Géraldine; Grand, Cécile; De-Vaufleury, Annette; Scheifler, Renaud Contamination of woody habitat soils around a former lead smelter in the North of France In: Science of the Total Environment, vol. 407, no. 21, pp. 5564-5577, 2009, (ACL). Abstract @article{Douay2009,
title = {Contamination of woody habitat soils around a former lead smelter in the North of France},
author = {Francis Douay and Christelle Pruvot and Christophe Waterlot and Clémentine Fritsch and Hervé Fourrier and Alexandre Loriette and Géraldine Bidar and Cécile Grand and Annette De-Vaufleury and Renaud Scheifler},
year = {2009},
date = {2009-01-01},
journal = {Science of the Total Environment},
volume = {407},
number = {21},
pages = {5564-5577},
abstract = {The Contamination of the Topsoil of 262 Woody Habitats around a Former Lead Smelter in the North of France Was Assessed. in This Urbanized and Industrialized Area, These Kinds of Habitats Comprise of Hedges, Groves, Small Woods, Anthropogenic Creations and One Large Forest. except for the Latter, Which Is 3 Km Away, These Woody Habitat Soils Often Present a High Anthropization Degree (a Significant Amount of Pebbles and Stones Related to Human Activities) with a High Metal Contamination. in the Studied Woody Habitat Topsoils, Cd, Pb and Zn Concentrations Largely Exceeded Those of Agricultural Topsoils Located in the Same Environmental Context. Therefore, Atmospheric Emissions from the Smelter Are Not the Only Cause of the High Contamination of the Woody Habitat Soils. This Last One Is Related to the Nature and the Contamination Level of Deposit in Relation with Human Activities (rubbles, Slag, Soils, Etc). with Regard to the Results Obtained with Chemical Extractions, the Mobility of Cd, Pb and Zn in These Soils Is Also Greater Than in Agricultural Soils. in the Forest, Pollutant Solubility Is Increased by Soil Acidic Ph. the Variability of the Physico-chemical Parameters and the High Metal Contamination of the Topsoils Are the Main Characteristics of the Woody Habitats Located around the Former Smelter. Although Never Taken into Account during Risk Assessment, the Disturbance of These Environmental Components Could Have Important Biogeochemical Impacts (nutrients and Metal Cycles). Moreover, Any Modification of the Soils' Use Could Potentially Cause Mobilization and Transfer of the Pollutants to the Biosphere. Six Years After the Closure of the Smelter, and As Social and Economic Pressures Considerably Increase in This Area, the Study of These Peculiar Ecosystems Is Necessary to Understand and Predict the Bioavailability, Transfer, Bioaccumulation and Effects of Pollutants in Food Chains.},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
The Contamination of the Topsoil of 262 Woody Habitats around a Former Lead Smelter in the North of France Was Assessed. in This Urbanized and Industrialized Area, These Kinds of Habitats Comprise of Hedges, Groves, Small Woods, Anthropogenic Creations and One Large Forest. except for the Latter, Which Is 3 Km Away, These Woody Habitat Soils Often Present a High Anthropization Degree (a Significant Amount of Pebbles and Stones Related to Human Activities) with a High Metal Contamination. in the Studied Woody Habitat Topsoils, Cd, Pb and Zn Concentrations Largely Exceeded Those of Agricultural Topsoils Located in the Same Environmental Context. Therefore, Atmospheric Emissions from the Smelter Are Not the Only Cause of the High Contamination of the Woody Habitat Soils. This Last One Is Related to the Nature and the Contamination Level of Deposit in Relation with Human Activities (rubbles, Slag, Soils, Etc). with Regard to the Results Obtained with Chemical Extractions, the Mobility of Cd, Pb and Zn in These Soils Is Also Greater Than in Agricultural Soils. in the Forest, Pollutant Solubility Is Increased by Soil Acidic Ph. the Variability of the Physico-chemical Parameters and the High Metal Contamination of the Topsoils Are the Main Characteristics of the Woody Habitats Located around the Former Smelter. Although Never Taken into Account during Risk Assessment, the Disturbance of These Environmental Components Could Have Important Biogeochemical Impacts (nutrients and Metal Cycles). Moreover, Any Modification of the Soils' Use Could Potentially Cause Mobilization and Transfer of the Pollutants to the Biosphere. Six Years After the Closure of the Smelter, and As Social and Economic Pressures Considerably Increase in This Area, the Study of These Peculiar Ecosystems Is Necessary to Understand and Predict the Bioavailability, Transfer, Bioaccumulation and Effects of Pollutants in Food Chains. |
2008Journal Article ER4 Auteurs : Bidar, Géraldine; Verdin, Anthony; Garçon, Guillaume; Pruvot, Christelle; Laruelle, Frédéric; Grandmougin-Ferjani, Anne; Douay, Francis; Shirali, Pirouz Changes in fatty acid composition and content of two plants (Lolium perenne and Trifolium repens) grown during 6 and 18 months in a metal (Pb, Cd, Zn) contaminated field In: Water Air and Soil Pollution, vol. 192, no. 1-4, pp. 281-291, 2008, (ACL). Abstract @article{Bidar2008,
title = {Changes in fatty acid composition and content of two plants (Lolium perenne and Trifolium repens) grown during 6 and 18 months in a metal (Pb, Cd, Zn) contaminated field},
author = {Géraldine Bidar and Anthony Verdin and Guillaume Garçon and Christelle Pruvot and Frédéric Laruelle and Anne Grandmougin-Ferjani and Francis Douay and Pirouz Shirali},
year = {2008},
date = {2008-01-01},
journal = {Water Air and Soil Pollution},
volume = {192},
number = {1-4},
pages = {281-291},
abstract = {The aim of this in situ study was to investigate the fatty acid (fa) composition and content in roots and shoots of lolium perenne and trifolium repens, grown under heavy metal stress (cd, pb, zn). the composition of fa was quite similar for the two plants and the two organs; main fa were palmitic acid (c16:0), oleic acid (c18:1), linoleic acid (c18:2) and linolenic acid (c18:3). for both plants, the major fa that characterized the roots was c18:2 whereas c18:3 was the prominent fa in shoots. for the first sampling (s1), in the roots of l. perenne and t. repens, polyunsaturated fatty acids (pufa) were affected by metal contamination while, in the second sampling (s2), pufa were affected in the shoots of the two plants. this alteration of pufa was well correlated with the bioaccumulation factor of metals which decreased in roots and increased in shoots with the time. moreover, a positive correlation was found between the pufa decrease and the malondialdehyde (mda) content, indicating the occurrence of a lipid peroxidation induced by the metal stress},
note = {ACL},
keywords = {ER4},
pubstate = {published},
tppubtype = {article}
}
The aim of this in situ study was to investigate the fatty acid (fa) composition and content in roots and shoots of lolium perenne and trifolium repens, grown under heavy metal stress (cd, pb, zn). the composition of fa was quite similar for the two plants and the two organs; main fa were palmitic acid (c16:0), oleic acid (c18:1), linoleic acid (c18:2) and linolenic acid (c18:3). for both plants, the major fa that characterized the roots was c18:2 whereas c18:3 was the prominent fa in shoots. for the first sampling (s1), in the roots of l. perenne and t. repens, polyunsaturated fatty acids (pufa) were affected by metal contamination while, in the second sampling (s2), pufa were affected in the shoots of the two plants. this alteration of pufa was well correlated with the bioaccumulation factor of metals which decreased in roots and increased in shoots with the time. moreover, a positive correlation was found between the pufa decrease and the malondialdehyde (mda) content, indicating the occurrence of a lipid peroxidation induced by the metal stress |
